Correlation between temperature activation of charge-carrier generation efficiency and hole mobility in small-molecule donor materials.

In organic solar cells, free charge carriers are generated at the interface between an electron-donating and an electron-accepting material. The detailed mechanisms of the generation of free charge carriers are still under discussion. In this work, we investigate the influence of temperature on the generation efficiency of free charge carriers in blends of dicyanovinyl substituted oligothiophene (DCVnT) molecules and C60 by quasi-steady-state photoinduced absorption (PIA) measurements.

Non-homogeneity of distribution of transport and trapping states in poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylenevinylene].

Carrier transport and trapping was investigated in poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylenevinylene] (MDMO-PPV) layers by thermally stimulated currents (TSC) depending on the exciting light spectral range. The upper edge of the spectra ranged from 1.77 eV up to 3.

Energy distribution of trapping and transport states in MDMO-PPV ([poly-(2-methoxyl, 5-(3,77dimethyloctyloxy)] para phenylenevinylene).

We have investigated charge carrier transport and trapping in the layers of [poly-(2-methoxyl, 5-(3,77dimethyloctyloxy)] para phenylenevinylene (MDMO-PPV). To reveal distribution of the trapping states the thermally stimulated current method was applied using the varying excitation conditions by light and applied voltage. To assure the selective excitation of the defect states close to the band gap edges, both extrinsic and intrinsic excitation by the light passed through the long-pass color filters with the cut-off energies ranging from 1.

Charge transport and trapping in bulk-heterojunction solar cells.

Charge carrier transport and trapping was investigated in organic solar cell structures consisting of poly-3-hexylthiophene blended with the fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester in 6:5 weight ratio. The analysed devices having solar efficiency of 3.7 per cent were produced in the inverted layer sequence.