Natural source zone depletion (NSZD) insights from over 15 years of research and measurements: A multi-site study.

Site-average Natural Source Zone Depletion (NSZD) rates measured from 40 petroleum light non-aqueous phase liquid (LNAPL) source zone sites were compiled from researchers, project reports, and scientific papers. At each site, the following data were compiled: i) general site location; ii) LNAPL fuel type; iii) measurement method, number of locations, and number of measurements per location; and iv) calculated site-average NSZD rate in liters per hectare per year (L/ha/yr) per site and the associated measurement method (i.e.

Real-time soil and groundwater monitoring via spatial and temporal resolution of biogeochemical potentials.

Oxidation-reduction potentials (ORP) govern the transformation of organic compounds in water and soils. Standard methods for measurements of ORPs in subsurface setting are deeply flawed due to heterogeneous samples from wells, failure to capture weakly poised redox couples, and biases with ex-situ measurements. In this study, we developed a real-time in-situ ORP sensor system that continuously measures biogeochemical electrical potentials using vertically distributed point sensing electrodes in direct contact with the soil.

Thermal estimation of natural source zone depletion rates without background correction.

Real-time monitoring of subsurface temperature profiles is a promising approach to resolving natural source zone depletion (NSZD) rates for shallow petroleum liquids. Herein, a new "single stick" computational method for transforming temperature data into NSZD rates is advanced. The method is predicated on subsurface temperatures being a function of surface heating and cooling, and the heat associated with NSZD.