Synthesis and characterization of 2-(anthracene-9-yl)-4,5-diphenyl-1-imidazole derivatives as environmentally sensitive fluorophores.

2-(Anthracene-9-yl)-4,5-diphenyl-1-imidazole (ADPI) provides an intriguing molecular platform for developing organic fluorophores with diverse properties and fluorescence performances. However, derivatives of ADPI have not yet been well explored and extensive studies are warranted. To shed more light on this, we have synthesized a series of π-extended ADPIs through a concise synthetic route involving an efficient cross-condensation reaction followed by Pd-catalyzed Suzuki cross-coupling.

Eco-friendly solvent bar microextraction based on a natural deep eutectic solvent and multivariate optimization for simultaneous determination of spironolactone and canrenone in urine and plasma samples.

Simultaneous measurement of spironolactone and canrenone in urine and plasma provides valuable insight into renal function, and therapeutic efficacy and can be utilized to identify potential health risks and ensure patient safety throughout treatment. By adopting greener methods to analyze these compounds, significant reductions in the environmental impact of such studies can be achieved. For this purpose, a sensitive and eco-friendly solvent bar microextraction method using natural deep eutectic solvent (NDE) followed by high-performance liquid chromatography-diode array detection (HPLC-DAD) was developed to determine spironolactone and canrenone in urine and plasma samples.

Selective removal of dibenzothiophene from commercial diesel using manganese dioxide-modified activated carbon: a kinetic study.

With a total concentration of 7055 mgS/kgfuel, the content of organosulphur compounds (OSCs) in local diesel is 20 times higher than the regulated value. Analysis revealed that 30% of OSC is originated from dibenzothiophene (DBT). It is known that DBT is a hardly removable compound and selective adsorbents are often needed for its removal with low affinity for other diesel components.

New palladium(II) complexes bearing pyrazole-based Schiff base ligands: synthesis, characterization and cytotoxicity.

Reactions of 5-hydrazino-1,3-dimethyl-4-nitro-1H-pyrazole (1) with substituted benzaldehydes (2-5) in methanol gave the new substituted benzaldehyde (1,3-dimethyl-4-nitro-1H-pyrazol-5-yl)hydrazone Schiff base ligands (6-9) benzaldehyde (1,3-dimethyl-4-nitro-1H-pyrazol-5-yl)hydrazone (H-BDH, 6), 2,3-dimethoxybenzaldehyde (1,3-dimethyl-4-nitro-1H-pyrazol-5-yl)hydrazone (MeO-BDH, 7), 4-chlorobenzaldehyde (1,3-dimethyl-4-nitro-1H-pyrazol-5-yl)hydrazone (Cl-BDH, 8), and 4-hydroxybenzaldehyde (1,3-dimethyl-4-nitro-1H-pyrazol-5-yl)hydrazone (OH-BDH, 9) in moderate to excellent yields. Reactions of these pyrazole-based Schiff bases with [PdCl(2)(NCPh)(2)] in acetone at room temperature gave the trans-palladium(II) complexes trans-[PdCl(2)(L)(2)] (10-13) (L=6-9). The isolated compounds were characterized by their physical properties, elemental analysis, IR-, MS (EI)- and NMR-spectroscopy.

4-(4-Chloro-phen-yl)-1-(2-hydr-oxy-2,2-di-phenyl-acet-yl)thio-semicarbazide.

The asymmetric unit of the title compound, C(21)H(18)ClN(3)O(2)S, contains two mol-ecules in which the bond lengths and angles are almost identical. Intra-molecular N-H⋯S hydrogen bonds result in the formation of two five-membered rings. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers; these dimers are linked via inter-molecular O-H⋯S hydrogen bonds, leading to infinite corrugated layers parallel to the bc plane through R(2) (2)(16) ring motifs.