Palladium (PdNTs) and gold nanotubes (AuNTs) were synthesized by the galvanic displacement of silver nanowires. PdNTs and AuNTs have wall thicknesses of 6 nm, outer diameters of 60 nm, and lengths of 5-10 and 5-20 μm, respectively. Rotating disk electrode experiments showed that the PdNTs and AuNTs have higher area normalized activities for the oxygen reduction reaction (ORR) than conventional nanoparticle catalysts.
View Article and Find Full Text PDFSilver nanowires (AgNWs) and nanoparticles (AgNPs) have been synthesized to facilitate hydroxide-exchange membrane fuel cell development and commercialization. AgNWs and AgNPs with variable diameters (25-60 nm AgNWs, 2.4-30 nm AgNPs) have been studied with rotating-disk electrode experiments to examine the impact of size and morphology on the oxygen reduction reaction (ORR).
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