Phytoglycogen (PG) is a polysaccharide produced in the kernels of sweet corn as soft, highly branched, compact nanoparticles. Its tree-like or dendritic architecture, combined with a high-safety profile, makes PG nanoparticles attractive for use in biological applications, many of which rely on the association or binding of small biomolecules. We have developed a methodology to functionalize surface plasmon resonance (SPR) sensor surfaces with PG nanoparticles, and we demonstrate the utility of the PG-functionalized SPR sensor by measuring the binding affinity of the tetrameric concanavalin A (ConA) protein to both native PG nanoparticles and smaller, softer acid-hydrolyzed PG nanoparticles.
View Article and Find Full Text PDFWe study the elastocapillary interaction between flexible microfibers in contact with bubbles trapped at the surface of a liquid bath. Microfibers placed on top of bubbles are found to migrate to and wrap into a coil around the perimeter of the bubble for certain bubble-fiber size combinations. The wrapping process is spontaneous: the coil spins atop the bubble, thereby drawing in excess fiber floating on the bath.
View Article and Find Full Text PDFWe report on the elastocapillary deformation of flexible microfibers in contact with liquid droplets. A fiber is observed to bend more as the size of the contacting droplet is increased. At a critical droplet size, proportional to the bending elastocapillary length, the fiber is seen to spontaneously wind around the droplet.
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