Crystal structure of di-chlorido-bis-{μ-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}{2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}cadmium(II)cobalt(III) monohydrate.

The title compound, [CoCd(CHNO)Cl]·HO, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova (2018 ▸). , , 171-184]. The current structure reveals different cell parameters and space group compared with the published one while both are monoclinic with almost the same cell volume.

Crystal structure of 4,10-dimeth-oxy-13-methyl-6,12-6,12-epimino-dibenzo[,][1,5]dioxocine.

The title compound, CHNO, lacks crystallographic symmetry with one mol-ecule per asymmetric unit. The mol-ecule exists in a folded butterfly-like conformation; the benzene rings form a dihedral angle of 84.72 (7)°.