Architecturally designed Pt-MoS2 and Pt-graphene composites for electrocatalytic methanol oxidation.

Thin films consisting of platinum nanoparticles (Pt NPs) with uniform size and distribution have been successfully prepared at a liquid-liquid interface. Apart from the usual substrates like glass, Si etc. the films were also deposited on the surfaces of MoS2 thin films and graphene nanosheets (GNS) respectively, by using a layer-by-layer (LbL) deposition technique to form Pt-MoS2 and Pt-GNS composites.

Reduced Graphene Oxide Composite with Oxidizable Manganese/Cobalt Mixed Oxide for p-Cresol Oxidation by Using Molecular Oxygen.

A composite of graphene oxide (GO) with mixed oxide (MnCo) was prepared by using a solvothermal method. During the synthesis, both the reduction of GO and growth of metal oxides took place simultaneously. The as-prepared composite material was highly selective for the liquid-phase oxidation of p-cresol to form p-hydroxybenzaldehyde in 71 % yield within 1 h.

Shape-selective oriented cerium oxide nanocrystals permit assessment of the effect of the exposed facets on catalytic activity and oxygen storage capacity.

The catalytic performance of a range of nanocrystalline CeO2 samples, prepared to have different morphologies, was measured using two accepted indicators; oxygen storage and diesel soot combustion. The same powders were characterized in detail by HR-TEM, XRD, XPS, and Raman methods. The study demonstrates that activity is determined by the relative fraction of the active crystallographic planes, not by the specific surface area of the powders.

A method to form semiconductor quantum dot (QD) thin films by igniting a flame at air-liquid interface: CdS and WO3.

We reveal an easy, inexpensive, efficient one stepflame synthesis of semiconductor/metal oxide thin films at air-liquid interface, subsequently, transferred on suitable substrate. The method has been illustrated by the formation of CdS and WO3 QDs thin films. The features of the present method are (1) Growth of thin films consisting of0.

Vapor-liquid-solid growth of one-dimensional tin sulfide (SnS) nanostructures with promising field emission behavior.

Single-crystalline ultralong tin sulfide (SnS) nanowires has been grown by a thermal evaporation technique under optimized conditions on gold-coated silicon substrates, and for the first time, field emission investigations on the SnS nanowires at the base pressure of 1 × 10(-8) mbar are reported. It has been revealed that the surface morphology of the as-synthesized SnS nanostructures is significantly influenced by the deposition temperature and duration. Structural and morphological analyses of as-synthesized SnS nanostructures have been carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM).

Mixed Co-Mn Oxide-Catalysed Selective Aerobic Oxidation of Vanillyl Alcohol to Vanillin in Base-Free Conditions.

Manganese-doped cobalt mixed oxide (MnCo-MO) catalyst was prepared by a solvothermal method. The as-prepared catalyst was characterised by X-ray photoelectron spectroscopy, H temperature-programmed reduction, O temperature-programmed oxidation and XRD. This catalyst gave 62 % conversion with 83 % selectivity to vanillin in 2 hours for the liquid-phase air oxidation of vanillyl alcohol without using base.

Ecofriendly synthesis and solar photocatalytic activity of S-doped ZnO.

The S-doped ZnO was prepared by new ecofriendly method, which involves simple mechanochemical synthesis followed by thermal decomposition of bisthiourea zinc oxalate (BTZO) powders. The BTZO was characterized by FTIR and TG-DTA analysis while S-doped ZnO crystallite was characterized by XRD, XPS, SEM, EDXS, and photoluminescence (PL) spectra. X-ray diffraction data suggest the single phase wurtzite structure for S-doped ZnO and the incorporation of sulfur expand the lattice constants of ZnO.

Preparation of thin films comprising palladium nanoparticles by a solid-liquid interface reaction technique.

A new approach to the formation of palladium nanoparticulate films with diameter between 6 and 50 nm by the solid-liquid interface reaction technique (SLIRT) has been presented. A solid film of palladium nitrate was formed by the modified spin coating method. This film is subsequently immersed in a reducing solution to initiate a reaction at the interface and ultimately transforms it to a palladium metal film.