A Monte Carlo Approach for Simulating Electrical Conductivity in Highly Porous Ceramic Composites: Impact of Internal Structure.

Porous ceramic composites play an important role in several applications. This is due to their unique properties resulting from a combination of various materials. Determination of the composite properties and structure is crucial for their further development and optimization.

Microporous Electrode Binders for Anion Exchange Membrane Water Electrolyzers.

In anion exchange membrane (AEM) water electrolyzers, AEMs separate hydrogen and oxygen, but should efficiently transport hydroxide ions. In the electrodes, catalyst nanoparticles are mechanically bonded to the porous transport layer or membrane by a polymeric binder. Since these binders form a thin layer on the catalyst particles, they should not only transport hydroxide ions and water to the catalyst particles, but should also transport the nascating gases away.

Elucidating the Complex Oxidation Behavior of Aqueous HPO on Pt Electrodes via Tender X-ray Absorption Near-Edge Structure Spectroscopy at the P -Edge.

tender X-ray absorption near-edge structure (XANES) spectroscopy at the P -edge was utilized to investigate the oxidation mechanism of aqueous HPO on Pt electrodes under various conditions relevant to high-temperature polymer electrolyte membrane fuel cell (HT-PEMFC) applications. XANES and electrochemical analysis were conducted under different tender X-ray irradiation doses, revealing that intense radiation induces the oxidation of aqueous HPO via HO yielding HPO and H. A broadly applicable experimental procedure was successfully developed to suppress these undesirable radiation-induced effects, enabling a more accurate determination of the aqueous HPO oxidation mechanism.

Cycloaliphatic Quaternary Ammonium Functionalized Poly(oxindole biphenyl) Based Anion-Exchange Membranes for Water Electrolysis: Stability and Performance.

Mechanically robust anion-exchange membranes (AEMs) with high conductivity and long-term alkali resistance are needed for water electrolysis application. In this work, aryl-ether free polyaromatics containing isatin moieties were prepared via super acid-catalyzed copolymerization, followed by functionalization with alkaline stable cyclic quaternary ammonium (QA) cationic groups, to afford high performance AEMs for application in water electrolysis. The incorporation of side functional cationic groups (pyrrolidinium and piperidinium) onto a polymer backbone via a flexible alkyl spacer aimed at conductivity and alkaline stability improvement.

Oxidation of Aqueous Phosphorous Acid Electrolyte in Contact with Pt Studied by X-ray Photoemission Spectroscopy.

The oxidation of the aqueous HPO in contact with Pt was investigated for a fundamental understanding of the Pt/aqueous HPO interaction with the goal of providing a comprehensive basis for the further optimization of high-temperature polymer electrolyte membrane fuel cells (HT-PEMFCs). Ion-exchange chromatography (IEC) experiments suggested that in ambient conditions, Pt catalyzes HPO oxidation to HPO with HO. X-ray photoelectron spectroscopy (XPS) on different substrates, including Au and Pt, previously treated in HPO solutions was conducted to determine the catalytic abilities of selected metals toward HPO oxidation.

Characterization of Commercial Polymer-Carbon Composite Bipolar Plates Used in PEM Fuel Cells.

Bipolar plates represent a crucial component of the PEM fuel cell stack. Polymer-carbon composites are recognized as state-of-the-art materials for bipolar plate manufacturing, but their use involves a compromise between electrical and heat conductivity, mechanical strength and costs. Thus, all key parameters must be considered when selecting a suitable plate satisfying the demands of the desired application.

Cost-efficient improvement of coking wastewater biodegradability by multi-stages flow through peroxi-coagulation under low current load.

Cost-effective pretreatment of the highly concentrated and biorefractory coking wastewater to improve biodegradability is of significant importance, while green electrochemical technologies without external chemicals addition are charming but still challenging due to its high energy consumption. In this work, a novel multi-stages flow through peroxi-coagulation (PC) was for the first time developed with graphite felt cathode modified by graphene, showing an excellent performance in removal of 71.5% COD, 72.

The effect of surface modification by reduced graphene oxide on the electrocatalytic activity of nickel towards the hydrogen evolution reaction.

To find cheap, efficient and durable hydrogen evolution reaction catalysts is one of the major challenges when developing an alkaline water electrolysis system. In this paper we describe an electrochemically reduced graphene oxide (RGO)-modified Ni electrode, which could be used as a pre-eminent candidate for such a system. The experimentally determined characteristics of this electrode showing superior electrocatalytic activity were complemented by density functional theory calculations.

Nonylphenol, octylphenol, and bisphenol-A in the aquatic environment: a review on occurrence, fate, and treatment.

This paper reviews the current knowledge on the occurrence, biodegradation, and photooxidation of nonylphenol (NP), octylphenol (OP), and bisphenol-A (BPA) in aquatic environment. Generally, the concentrations determined were 0.006-32.

A combination of ion exchange and electrochemical reduction for nitrate removal from drinking water. Part II: electrochemical treatment of a spent regenerant solution.

The process of electrochemical treatment of a solution after strong basic anion exchanger regeneration was studied. The goal of the study was to reduce the nitrate content in the solution to allow its use in a closed loop. Diaphragmless, flow-through cells in a recirculation mode with and without a fluidizing bed of inert particles in the interelectrode space equipped with copper (Cu) cathodes and activated titanium anodes were used.

A combination of ion exchange and electrochemical reduction for nitrate removal from drinking water. Part I: nitrate removal using a selective anion exchanger in the bicarbonate form with reuse of the regenerant solution.

The process of selective nitrate removal from drinking water by means of ion exchange was studied. A commercial strong base anion exchanger with triethylammonium (-N+Et3) functional groups was used in the bicarbonate (HCO3-) and carbonate (CO3(2-)) form. The aim of this study was to optimize ion-exchanger regeneration in view of the subsequent electrochemical reduction of nitrates in the spent regenerant solution.