This work describes the development of a novel fluorescence sensor based on magnesium/S@g-CN nanosheets for selective detection of copper (Cu) ions in water. Mg/S@g-CN nanosheets were prepared by the polycondensation technique and investigated by X-ray diffraction (XRD), ATR-FTIR spectroscopy, scanning electron microscopy (SEM), surface area (BET), and UV-Vis optical absorption measurements. XRD and ATR-FTIR analysis showed the characteristic peaks for S@g-CN.
View Article and Find Full Text PDFThe optical properties of polyvinylidene fluoride (PVDF) polymer nanocomposite films incorporating SrTiO/carbon nanotubes (CNTs) as nanofillers are investigated. PVDF/SrTiO/CNTs films were prepared by the solution casting technique. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) analyses confirmed the incorporation of SrTiO/CNTs into the PVDF matrix.
View Article and Find Full Text PDFWater pollution by synthetic anionic dyes is one of the most critical ecological concerns and challenges. Therefore, there is an urgent need to find an efficient adsorbent and photocatalyst for dye removal. In the present study, we aimed to fabricate a hybrid mesoporous composite of spongy sphere-like SnO and three-dimensional (3D) cubic-like MgO (SnO/MgO) as a promising adsorbent/photocatalyst to remove the anionic sunset yellow (SSY) dye from real wastewater at neutral pH conditions.
View Article and Find Full Text PDFIn light of the variety of industrial uses and economic relevance of mild steel, corrosion resistance is a serious topic. Utilization of inhibitors serves as one of the most essential methods for corrosion control. Two thiadiazole compounds, namely, 2-amino-5-(4-bromobenzyl)-1,3,4-thiadiazole () and 2-amino-5-(3-nitrophenyl)-1,3,4-thiadiazole (), were synthesized.
View Article and Find Full Text PDFIn recent years, the detection of water pollution with low levels of heavy metals has attracted the great attention of many researchers as a result of the imminent danger of this type of pollution to all mankind. Meanwhile, we introduce a theoretical approach based on the one-dimensional phononic crystals (1D-PnCs) with a central defect layer as a novel platform for the highly sensitive detection of heavy metal pollution in freshwater. Therefore, the creation of a resonant peak in the transmittance spectrum related to this defect layer is highly conceivable.
View Article and Find Full Text PDFOxygen and hydrogen generated by water electrolysis may be utilized as a clean chemical fuel with high gravimetric energy density and energy conversion efficiency. The hydrogen fuel will be the alternative to traditional fossil fuels in the future, which are near to exhaustion and cause pollution. In the present study, flowery-shaped InMnSe nanoelectrocatalyst is fabricated by anion exchange reaction directly grown on nickel foam (NF) in 1.
View Article and Find Full Text PDFWell-organized water splitting semiconducting photocatalyst is an important concept, but stimulating aimed at decisive energy and environmental emergencies. In this context, visible light-based photocatalytic water splitting with low-dimensional semiconducting materials is proposed to produce sustainable energy. Here we optimized the sequential of organic electron-rich heterocyclic monomer namely benzothiadiazole (BTD) quenched within polymeric carbon nitride (PCN) semiconductor via copolymerization, thereby assembling a sanctum of donor-π-acceptor (D-π-A) photocatalysts.
View Article and Find Full Text PDFLight-driven heterogeneous photocatalysis has gained great significance for generating solar fuel; the challenging charge separation process and sluggish surface catalytic reactions significantly restrict the progress of solar energy conversion using a semiconductor photocatalyst. Herein, we propose a novel and feasible strategy to incorporate dihydroxy benzene (DHB) as a conjugated monomer within the framework of urea containing CN (CNU-DHBx) to tune the electronic conductivity and charge separation due to the aromaticity of the benzene ring, which acts as an electron-donating species. Systematic characterizations such as SPV, PL, XPS, DRS, and TRPL demonstrated that the incorporation of the DHB monomer greatly enhanced the photocatalytic CO reduction of CN due to the enhanced charge separation and modulation of the ionic mobility.
View Article and Find Full Text PDF