Nano trigonal prismatic BaCoO with hierarchical structure and deficient BaCoO with columnar structure have been prepared at low temperatures (400 [BC4] and 500 [BC5]) °C/3h using green method. X-ray diffraction (XRD) results demonstrate the presence of enriched BaCoO phase at 400 °C and multiphase structures: BaCoO, BaCoO, and CoO with a decrease in the amount of BaCoO at 500 °C. The prepared powders are characterized by a high specific surface area (SSA) values which are reflected to the mode of synthesis that leads to produce materials with massive active sites.
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