Publications by authors named "Kanna Suzuki"
Article Synopsis
- A method for one-pot Julia olefination using ribofuranosyl sulfones was developed, producing α-anomers with complete α-selectivity through a specific glycosylation process.
- The reaction with aldehydes yielded thermodynamically less stable α-glycals with high stereoselectivity, especially notable with aromatic aldehydes.
- The study highlighted the influence of anomeric configuration on stereoselectivity in the olefination, supported by density functional theory (DFT) calculations, and demonstrated effective protection of products using a 2-cyanoethyl group.
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