Spark plasma sintered porous Ni as a novel substrate of NiSe@Ni self-supporting electrode for ultra-durable hydrogen evolution reaction.

Developing efficient and durable self-supporting catalytic electrodes is an important way for industrial applications of hydrogen evolution reaction. Currently, commercial nickel foam (NF)-based electrode has been widely used due to its good catalytic performance. However, the NF consisting of smooth skeleton surface and large pores not only exhibits poor conductivity but also provides insufficient space for catalyst decoration and sufficient adhesion, resulting in inadequate catalytic performance and poor durability of NF-based electrodes.

One-step Sintering Synthesis of NiSe-Ni Electrode with Robust Interfacial Bonding for Ultra-stable Hydrogen Evolution Reaction.

Exploring efficient and robust self-supporting hydrogen evolution reaction (HER) electrodes using simple, accessible, and low-cost synthetic processes is crucial for the commercial application of water electrolysis at high current densities. Ni-based self-supporting electrodes are widely studied owing to their low cost and good catalytic performance. However, to date, the preparation of Ni-based electrodes requires multistep and complex preparation processes.