Publications by authors named "Kamila Gryko"

The aim of this study was to outline the relationships between selected parameters connected with lifestyle and serum anti-Müllerian hormone (AMH) levels, i.e., a marker of ovarian reserve.

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Complexes of chlorogenic acid (5-CQA) with copper(II) and iron(III) were synthesized in a solid state and examined by means of FT-IR, thermogravimetric, and elemental analyses. The molar stoichiometric ratios of metal:ligand for the solid forms of the complexes were established as Cu(II):L = 1:2 and Fe(III):L = 2:3 (L: 5-CQA), with the possible coordination through the carboxylate group and the hydroxyl group from the catechol moiety. In an aqueous solution at pH = 7.

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Article Synopsis
  • The study analyzed the structural, antioxidant, and pro-oxidant properties of four compounds: cinnamic acid, 4-hydroxycinnamic acid, caffeic acid, and 3,4,5-trihydroxycinnamic acid.
  • Various analytical techniques, including FT-IR and UV/Vis, were used to investigate how the number and placement of hydroxyl groups affect the molecular structure and antioxidant capabilities of these compounds.
  • The research also explored the compounds' potential impact on biodegradability and their role in enhancing carbon and nitrogen transformations in biological wastewater treatment.
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The copper (II) complex of ursolic acid (Cu(II) UA) was synthesized and discussed in terms of its infrared, UV-visible spectra, quantum-chemical calculations at B3LYP/6-31G(d) level and antioxidant capacity. The copper (II) complex was stable in methanolic solution with the molar ratio metal:ligand 1:1. The data obtained by FT-IR confirmed the metal ion coordination through the carboxylate anion.

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In this study the peels of ecologically grown apple (Malus domestica) cultivars: Gold Milenium (a new scab-resistant variety) and Papierowka (Papirovka; an old, sensitive to apple scab variety) were examined for their composition (phenolic compounds, triterpenoids, simple organic acids, macro-, microelements, reducing sugars, L-ascorbic acid), pro- and antioxidant properties as well as their application in reduction of the oxidative stress in cultured human skin fibroblast. The higher content of phenolic compounds correlated with the greater pro- and antioxidant activity of the peels of Papierowka compared to Gold Milenium in DPPH·, ABTS, FRAP and CUPRAC assays as well as an ability to inhibition of lipid peroxidation. The quantity of the compounds strongly depended on the type of extraction.

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