Aerobic biodegradation of emerging azole contaminants by return activated sludge and enrichment cultures.

Azoles are an emerging class of contaminants with a growing ubiquitous presence in the environment. This study investigates the aerobic microbial degradation of four azoles, pyrazole (PA), 1,2,4-triazole (TA), benzotriazole (BTA) and 5-methylbenzotriazole (5-MBTA), with return activated sludge and microbial enrichment cultures. Slow degradation of PA was observed in the presence of glucose and NH with a peak degradation rate of 0.

Bacteria Make a Living Breathing the Nitroheterocyclic Insensitive Munitions Compound 3-Nitro-1,2,4-triazol-5-one (NTO).

The nitroheterocyclic 3-nitro-1,2,4-triazol-5-one (NTO) is an ingredient of insensitive explosives increasingly used by the military, becoming an emergent environmental pollutant. Cometabolic biotransformation of NTO occurs in mixed microbial cultures in soils and sludges with excess electron-donating substrates. Herein, we present the unusual energy-yielding metabolic process of NTO respiration, in which the NTO reduction to 3-amino-1,2,4-triazol-5-one (ATO) is linked to the anoxic acetate oxidation to CO by a culture enriched from municipal anaerobic digester sludge.

Rapid biotransformation of the insensitive munitions compound, 3-nitro-1,2,4-triazol-5-one (NTO), by wastewater sludge.

As the use of the new insensitive munitions compound 3-nitro-1,2,4-triazol-5-one (NTO) increases, wastewaters, runoff and groundwater containing NTO will be generated. Little is known about the fate of NTO during biological wastewater treatment. The objective of this study was to explore the ability of wastewater sludges to promote the biotransformation of NTO.

Diazole and triazole inhibition of nitrification process in return activated sludge.

Azoles are emerging contaminants that are resistant to biodegradation during wastewater treatment. Their presence has been widely reported in wastewater effluents and receiving waters. In this work, the potential inhibition of nitrification process by six different azole compounds in wastewater treatment plants was investigated in batch bioassays.

Microbial Enrichment Culture Responsible for the Complete Oxidative Biodegradation of 3-Amino-1,2,4-triazol-5-one (ATO), the Reduced Daughter Product of the Insensitive Munitions Compound 3-Nitro-1,2,4-triazol-5-one (NTO).

3-Nitro-1,2,4-triazol-5-one (NTO) is one of the main ingredients of many insensitive munitions, which are being used as replacements for conventional explosives. As its use becomes widespread, more research is needed to assess its environmental fate. Previous studies have shown that NTO is biologically reduced to 3-amino-1,2,4-triazol-5-one (ATO).