Selective immobilization of Pb(II) by biogenic whewellite and its mechanism.

The development of bio-adsorbents with highly selective immobilization properties for specific heavy metals is a great challenge, but has important application value. Biogenic whewellite (BW) with high selectivity for Pb(II) was synthesized by mineral microbial transformation. The selective immobilization properties and mechanism of BW for Pb(II) were analyzed by combining mineral characterization technology and batch adsorption research methods.

Difference Analysis of the Composition of Iron (Hydr)Oxides and Dissolved Organic Matter in Pit Mud of Different Pit Ages in Luzhou Laojiao and Its Implications for the Ripening Process of Pit Mud.

Long-term production practice proves that good liquor comes out of the old cellar, and the aged pit mud is very important to the quality of Luzhou-flavor liquor. X-ray diffraction, Fourier transform ion cyclotron resonance mass spectrometry, and infrared spectroscopy were used to investigate the composition characteristics of iron-bearing minerals and dissolved organic matter (DOM) in 2-year, 40-year, and 100-year pit mud and yellow soil (raw materials for making pit mud) of Luzhou Laojiao distillery. The results showed that the contents of total iron and crystalline iron minerals decreased significantly, while the ratio of Fe(II)/Fe(III) and the content of amorphous iron (hydr)oxides increased significantly with increasing cellar age.