Joint probabilistic risk of organic micropollutants in the aquaculture seawater around Liaodong Peninsula.

The limited number of organic micropollutants (OMPs) investigated in aquaculture seawater may underestimate the risk to marine organisms. It is critical to comprehensively investigate the occurrence of diverse OMPs in mariculture area and assess their joint risks to coastal marine organisms. Herein, the joint risks caused by multiple substances were assessed based on the screened results of approximately 1300 non-polar to polar OMPs in the seawater of mariculture ponds and raft culture areas around Liaodong Peninsula.

Occurrence and Health Risks of Organic Micropollutants in Tap Water in Dalian.

Organic micropollutants (OMPs) in tap water may pose risks to human health. Previous studies on the potential health risks of OMPs in tap water may have underestimated the potential health risks of OMPs due to their limited coverage in target pollutants and incomplete toxicity data. In this study, tap water samples were collected in 37 sampling sites in Dalian, China.

Occurrence, potential sources, and risk assessment of pharmaceuticals and personal care products in atmospheric particulate matter in Hanoi, Vietnam.

Pharmaceutical and personal care products (PCPPs) were recently recognized as emerging pollutants due to their potential for adverse health and environmental impacts. One potential route of exposure, atmospheric particulate matter (APM), for polar PPCP chemicals has to date received limited attention. This study screened for 190 polar PPCP chemicals in outdoor APM samples collected from two locations in Hanoi, Vietnam, and predictions of source and potential effects on human health are presented.

Novel automated identification and quantification database using liquid chromatography quadrupole time-of-flight mass spectrometry for quick, comprehensive, cheap and extendable organic micro-pollutant analysis in environmental systems.

In order to protect human health and the environment, highly efficient, low-cost, labor-saving, and green analysis of toxic chemicals are urgently required. To achieve this objective, we have developed a novel database-based automated identification and quantification system (AIQS) using LC-QTOF-MS. Since the AIQS uses retention times (RTs), exact MS and MS-MS spectra, and calibration curves of 484 chemicals registered in the database instead of the use of standards, the targets can be determined with low-cost in a short time.

Sediment contamination with polybrominated diphenyl ethers and alternative brominated flame retardants: case study in urban lakes of Hanoi, Vietnam.

Information regarding the contamination of brominated flame retardants (BFRs) in lake sediments from Vietnam and Southeast Asia is still very limited. To fill such knowledge gaps, surface sediment samples from five urban lakes in Hanoi, Vietnam, were analyzed for polybrominated diphenyl ethers (PBDEs) and some other BFRs. Concentrations of total PBDEs ranged from 1.

In situ calibration of passive sampling methods for urban micropollutants using targeted multiresidue GC and LC screening systems.

In this study, Chemcatcher (CC) and Polar Organic Chemical Integrative Samplers (POCIS) passive samplers were chosen to investigate trace organic chemical residues in urban streams of the megacity of Sydney, Australia. In situ calibration with these passive samplers investigated 1392 organic chemicals. Six sets of CC passive samplers fitted with SDB-XC or SDB-RPS disks and six POCIS containing Oasis HLB sorbent were deployed at three sites.

Distribution and health risks of organic micropollutants from home dusts in Malaysia.

Indoor dust is an important medium to evaluate human exposure to emerging organic contaminants. The principal aim of this study was to determine overall status of organic micropollutants (OMPs) of indoor dust in Kuala Lumpur, Malaysia and assess their corresponding health risks. One hundred thirty-three OMPs, ascribed to 13 chemical groups, were screened by Automated Identification and Quantification System with a GC-MS database.

The rapid survey method of chemical contamination in floods caused by Typhoon Hagibis by combining in vitro bioassay and comprehensive analysis.

A novel comprehensive assessment system, consisting of a bioassay and chemical analysis, was developed to quickly evaluate the human health risk posed by toxic chemicals discharged due to natural disasters. To analyze samples quickly, a yeast-two-hybrid assay (Y2H) and GC-MS equipped with an automated identification and quantification system (AIQS-GC) were employed for the bioassay and chemical analysis, respectively. Since the analysis of 1000 substances by AIQS could be finished within two days following the Y2H assay for screening, this method would complete the risk assessment within three days.

Occurrence and exposure risk assessment of organic micropollutants in indoor dust from Malaysia.

Indoor dust is an important source of human exposure to hazardous organic micropollutants (OMPs) because humans spend about 90 % of their time in the indoor environments. This study initially analyzed the concentrations and compositions of OMPs in the dust of different indoor environments from Kuala Lumpur, Malaysia. A total of 57 OMPs were detected and assigned to 7 chemical classes in this study.

Comprehensive analyses of agrochemicals affecting aquatic ecosystems: A case study of Odonata communities and macrophytes in Saga Plain, northern Kyushu, Japan.

The negative influence of agrochemicals (pesticides: insecticide, fungicide, and herbicide) on biodiversity is a major ecological concern. In recent decades, many insect species are reported to have rapidly declined worldwide, and pesticides, including neonicotinoids and fipronil, are suspected to be partially responsible. In Japan, application of systemic insecticides to nursery boxes in rice paddies is considered to have caused rapid declines in Sympetrum (Odonata: Libellulidae) and other dragonfly and damselfly populations since the 1990s.

Quinolone Signals Related to Quinolone Signal-Quorum Sensing Inhibits the Predatory Activity of .

is one of the predatory bacteria; therefore, it can act as a novel "living antibiotic," unlike the current antibiotics. Here the predation of by was inhibited in the presence of . This study investigated whether -induced predation inhibition is associated with bacterial quorum sensing (QS).

Evaluation of identification accuracy using AIQS for GC-MS for measuring heavily contaminated samples.

Automated identification and quantification systems with gas chromatography-mass spectrometry (GC-MS) (i.e., AIQS-GC) are used as a simple and comprehensive method for screening chemicals existing in the environment and are expected to be useful for emergency surveys in the event of a disaster.

Screening and ecological risk of 1200 organic micropollutants in Yangtze Estuary water.

The Yangtze River, the third largest river in the world, has been polluted by various organic chemicals. In 2018, China decided to implement ecological restoration of the Yangtze River to protect the river. However, except for some conventional pollution indices such as COD (Chemical Oxygen Demand) and NH-N, the overall levels and risks of a wide variety of organic micropollutants (OMPs) in the Yangtze Estuary is not clear.

An overview of organic contaminants in indoor dust, their health impact, geographical distribution and recent extraction/analysis methods.

People spend a substantial proportion of their time indoors; therefore, exposure to contaminants in indoor dust is persistent and profuse. According to the findings of recent studies, contaminants such as flame retardants (FRs), organochlorines (OCs), and phthalate esters (PAEs) are more prevalent in indoor dust. The discrepancy in the geographical distribution of these chemicals indicates country-specific applications.

Occurrence and ecological risks of 156 pharmaceuticals and 296 pesticides in seawater from mariculture areas of Northeast China.

China is the largest mariculture producer in the world. In recent years, pharmaceuticals and pesticides have been widely used in mariculture activities; however, most studies have only focused on the occurrence of limited types of antibiotics and organochlorine pesticides. It is critical to comprehensively investigate the occurrence of pharmaceuticals and pesticides in mariculture areas and assess their potential impacts on ocean ecosystems.

Occurrence and risk assessment of herbicides and fungicides in atmospheric particulate matter in Hanoi, Vietnam.

Vietnam is a Southeast Asian developing country with rapidly increasing air pollution, especially in large cities. Over 350,000 chemicals and chemical mixtures are produced and used in Vietnam; however, the country has only implemented air quality standards for 44 substances, which are primarily focused on inorganic and volatile organic compounds. Although numerous pesticides are frequently applied across large cities in Vietnam, information on their concentrations in atmospheric particulate matter (APM) is limited.

Contamination status, emission sources, and human health risk of brominated flame retardants in urban indoor dust from Hanoi, Vietnam: the replacement of legacy polybrominated diphenyl ether mixtures by alternative formulations.

This study investigated the occurrence, distribution of several additive brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs) and some novel brominated flame retardants (NBFRs) in urban indoor dust collected from ten inner districts of Hanoi, Vietnam to assess the contamination status, emission sources, as well as their associated human exposure through indoor dust ingestion and health risks. Total concentrations of PBDEs and NBFRs in indoor dust samples ranged from 43 to 480 ng g (median 170 ng g) and from 56 to 2200 ng g (median 180 ng g), respectively. The most abundant PBDE congener in these dust samples was BDE-209 with concentrations ranging from 29 to 360 ng g, accounting for 62.

Development of a rapid and comprehensive method for identifying organic micropollutants with high ecological risk to the aquatic environment.

Currently, tens-of-thousands of chemicals are used in Japan, and their presence in and impact on aquatic ecosystems are poorly understood. Because conventional risk evaluation processes using target analysis and biological tests are time-consuming and costly, it is challenging to investigate all substances. Therefore, we aimed to develop a rapid and highly efficient screening scheme for identifying hazardous organic micropollutants (OMPs) in aquatic ecosystems.

Use of comprehensive target analysis for determination of contaminants of emerging concern in a sediment core collected from Beppu Bay, Japan.

In recent years, concern about the release of anthropogenic organic micropollutants referred to as contaminants of emerging concern (CECs) has been growing. The objective of this study was to find potential CECs by means of an analytical screening method referred to as comprehensive target analysis with an automated identification and quantification system (CTA-AIQS), which uses gas and liquid chromatography combined with mass spectrometry (GC-MS and LC-QTOF-MS). We used CTA-AIQS to analyze samples from a sediment core collected in Beppu Bay, Japan.

Comprehensive study of insecticides in atmospheric particulate matter in Hanoi, Vietnam: Occurrences and human risk assessment.

Air pollution is the most serious environmental issue in Vietnam, particularly in big cities. Air pollutants that are set as environmental standards are regularly monitored by the public institutions. Whereas, environmental data on organic micro-pollutants in atmospheric particulate matters (APMs) is limited, including PAHs and POPs.

Occurrence and Health Risks of Organic Micro-Pollutants and Metals in Groundwater of Chinese Rural Areas.

Background: Groundwater is a main drinking-water source for Chinese rural residents. The overall pollution status of organic micropollutants (OMPs) and metals in the groundwater and corresponding health risks are unknown.

Objectives: Our objective was to comprehensively screen for and assess the health risks of OMPs and metals in groundwater of rural areas in China where groundwater is used for drinking so as to provide a benchmark for monitoring and improving groundwater quality in future developments.

Screening of 484 trace organic contaminants in coastal waters around the Liaodong Peninsula, China: Occurrence, distribution, and ecological risk.

Human activities such as agriculture, aquaculture, and industry can lead to the pollution of coastal waters by trace organic contaminants (TrOCs), and the TrOCs can pose a threat to marine ecosystems. Therefore, it is essential to investigate the occurrence, distribution, and ecological risk of the TrOCs in coastal waters. Previous studies adopting conventional analytical methods have focused on a limited number of targets.

Occurrences of microorganic pollutants in the Kumho River by a comprehensive target analysis using LC-Q/TOF-MS with sequential window acquisition of all theoretical fragment ion spectra (SWATH).

In this study, simultaneous identification and semi-quantification of hundreds of micropollutant compounds, including pharmaceutical and personal care products (PPCPs) and pesticides were performed in river and effluent samples from the Kumho River Basin using liquid chromatography quadrupole time-of-flight mass spectrometry (LC-Q-TOF/MS) with sequential window acquisition of all theoretical fragment ion spectra (SWATH). In total, 85 compounds (29 pesticides and 56 PPCPs) were identified. The highest proportions of PPCP residues were detected in the downstream area of the Kumho River, close to the central city.

Comprehensive Target Analysis for 484 Organic Micropollutants in Environmental Waters by the Combination of Tandem Solid-Phase Extraction and Quadrupole Time-of-Flight Mass Spectrometry with Sequential Window Acquisition of All Theoretical Fragment-Ion Spectra Acquisition.

There are many thousands of chemicals in use for a wide range of purposes, and highly efficient analytical methods are required to monitor them for protection of the environment. In order to cope with this difficult task we developed a novel, comprehensive method for 484 substances in water samples. In this method target chemicals were extracted by tandem SPE and then determined by LC-QTOF-MS-SWATH.

Development of a novel scheme for rapid screening for environmental micropollutants in emergency situations (REPE) and its application for comprehensive analysis of tsunami sediments deposited by the great east Japan earthquake.

The tsunami triggered by the Great East Japan Earthquake of March 2011, the strongest quake ever recorded in Japan, deposited tsunami sediments along the coastline of the affected area. Because the sediments contained a wide variety of hazardous chemicals, including organic micropollutants, a method for rapidly evaluating the environmental and human health risks of such chemicals is necessary. For this purpose, we propose a novel three-step scheme designated "rapid screening for environmental micropollutants in emergency situations (REPE)".