Size-controlled liquid phase synthesis of colloidally stable CoO nanoparticles.

Spinel cobalt(ii,iii) oxide (CoO) represents a p-type semiconductor exhibiting promising functional properties in view of applications in a broad range of technological fields including magnetic materials and gas sensors as well as sustainable energy conversion systems based on photo- and electrocatalytic water splitting. Due to their high specific surface area, nanoparticle-based structures appear particularly promising for such applications. However, precise control over the diameter and the particle size distribution is required to achieve reproducible size-dependent properties.

Combining Endovascular Aneurysm Sealing with Chimney Grafts - 5 Year Follow-Up after 47 Procedures.

Background: To evaluate longer-term results of a cohort treated with primary chimney endovascular aneurysm sealing (ChEVAS) for complex abdominal aortic aneurysms or secondary ChEVAS after failed endovascular aneurysm repair/endovascular aneurysm sealing.

Methods: A single-center study was conducted of 47 consecutive patients (mean age 72 ± 8 years, range 50-91; 38 men) treated with ChEVAS from February 2014 to November 2016 and followed through December 2021. The main outcome measures were all-cause mortality (ACM), aneurysm-related mortality, occurrence of secondary complications and conversion to open surgery.

Artificial Intelligence Outperforms Kaplan-Meier Analyses Estimating Survival after Elective Treatment of Abdominal Aortic Aneurysms.

Objective: Long term differences in survival after elective repair of abdominal aortic aneurysms (AAAs) between open surgical repair (OSR) and endovascular aneurysm repair (EVAR) are unclear, and hitherto artificial intelligence has not been used for this purpose. The aim was to compare the precision of survival estimates between the Kaplan-Meier (KM) method and the artificial intelligence derived method Neural Multi-Task Logistic Regression (N-MTLR), and to compare survival estimates as a function of patient age and time since surgery between OSR and EVAR using N-MTLR.

Methods: All AAAs between 2003 and 2018 in Denmark were identified in the Danish vascular registry.

How Temperatures May Affect the Synthesis of Fatty Acids during Olive Fruit Ripening: Genes at Work in the Field.

A major concern for olive cultivation in many extra-Mediterranean regions is the adaptation of recently introduced cultivars to environmental conditions different from those prevailing in the original area, such as the Mediterranean basin. Some of these cultivars can easily adapt their physiological and biochemical parameters in new agro-environments, whereas others show unbalanced values of oleic acid content. The objective of this study was to evaluate the effects of the thermal regime during oil synthesis on the expression of fatty acid desaturase genes and on the unsaturated fatty acid contents at the field level.

Non-traumatic Spontaneous Paraplegia Secondary to Thoracic Disc Herniations in the Setting of Tobacco Abuse and COVID-19: A Case Report and Literature Review.

Thoracic disc herniations (TDHs) are very rare. While most common in the setting of trauma, other etiologies have been documented. Here, we present a case of spontaneous TDHs in the setting of tobacco abuse and coronavirus disease 2019 (COVID-19) causing acute paraplegia.

Wind field reconstruction with adaptive random Fourier features.

We investigate the use of spatial interpolation methods for reconstructing the horizontal near-surface wind field given a sparse set of measurements. In particular, random Fourier features is compared with a set of benchmark methods including kriging and inverse distance weighting. Random Fourier features is a linear model approximating the velocity field, with randomly sampled frequencies and amplitudes trained to minimize a loss function.

Tunable dual-comb spectrometer for mid-infrared trace gas analysis from 3 to 4.7 µm.

Dual-frequency comb spectroscopy has emerged as a disruptive technique for measuring wide-spanning spectra with high resolution, yielding a particularly powerful technique for sensitive multi-component gas analysis. We present a spectrometer based on two electro-optical combs with subsequent conversion to the mid-infrared via tunable difference frequency generation, operating in the range from 3 to 4.7 µm.

Use of O-arm With Intraoperative Arteriography for Localization and Stealth Navigation of the Vertebral Arteries During Posterior Cervical Spine Surgery.

Background: Vertebral artery injury (VAI) can be a devastating complication during cervical spine surgery. Although considered a rare occurrence overall, incidences of VAI have been reported in the ranges of 0.07% to 8%.

Nonlinear interferometer for Fourier-transform mid-infrared gas spectroscopy using near-infrared detection.

Nonlinear interferometers allow for mid-infrared spectroscopy with near-infrared detection using correlated photons. Previous implementations have demonstrated a spectral resolution limited by spectrally selective detection. In our work, we demonstrate mid-infrared transmission spectroscopy in a nonlinear interferometer using single-pixel near-infrared detection and Fourier-transform analysis.

Open Conversion After Endovascular Aneurysm Sealing: Technical Features and Clinical Outcomes in 44 Patients.

Purpose: To evaluate the technical features and clinical results after open conversion for complications following endovascular aneurysm sealing (EVAS).

Materials And Methods: From July 2013 to February 2020, 44 patients (mean age 72±8 years; 36 men) underwent an open conversion due to EVAS complications in a single center. Data were collected on patient characteristics, reasons for conversion, characteristics and duration of the procedure, condition of the polymer, blood loss, time in the intensive care unit (ICU), and intra/postoperative complications.

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On occasion of the 200th anniversary of the birthday of Hermann von Helmholtz the article presents a historical review on the development of audiology over the past two centuries. Modern audiology is considered to be a multidisciplinary field addressing clinical work and research on all aspects of hearing impairment, particularly prevention/protection, diagnostics and treatment of hearing problems as well as rehabilitation of patients with any degree of hearing loss. To cover all these subjects comprehensively would go beyond the scope of a journal article.

Primary Cranial Vault Non-Hodgkin's Lymphoma Mimicking Meningioma With Positive Angiography.

Primary non-Hodgkin's lymphoma of the bone remains an uncommon presentation of non-Hodgkin's lymphoma. Primary lymphoma of the cranial vault is exceptionally rare. Here, we present a 62-year-old immunocompetent male presenting with the rapid growth of a left parietal scalp lesion and new-onset seizure.

The Correlation of Burnout and Optimism among Medical Residents.

Introduction Burnout is common among clinical specialties and has implications on the residents' well-being and mental health. Evidence suggests that optimism and burnout are correlated, but research has not focused on the applicability to medical residents. The objective of the study was to define burnout in residents and correlate it with optimism.

Fourier transform infrared spectroscopy with visible light.

Nonlinear interferometers allow spectroscopy in the mid-infrared range by detecting correlated visible light, for which non-cooled detectors with higher specific detectivity and lower dark count rates are available. We present a new approach for the registration of spectral information, which combines a nonlinear interferometer using non-degenerate spontaneous parametric down-conversion (SPDC) with a Fourier-transform spectroscopy concept. In order to increase the spectral coverage, we use broadband non-collinear SPDC in periodically poled LiNbO.

C2-3 Fracture Dislocation and Bilateral Vertebral Artery Occlusion Without Neurological Injury: A Case Report.

A 27-year-old female involved a motor vehicle collision as the restrained driver presented to the ER with agonal breathing and a Glasgow Coma Scale (GCS) of 3. Radiographic imaging demonstrated C2-3 craniocaudal dislocation, bilateral C2 comminuted pedicle fractures extending through the transverse foramina, complete bilateral vertebral artery occlusion, and negative signs of stroke with MRI. After halo immobilization, surgical stabilization, and medical treatment the patient was discharged and at her six-month follow up she was without neurological deficit.

Riociguat for the Treatment of Raynaud's Phenomenon: A Single-Dose, Double-Blind, Randomized, Placebo-Controlled Cross-Over Pilot Study (DIGIT).

Background And Objective: Raynaud's phenomenon (RP) is characterized by transient digital ischemia and is commonly associated with connective tissue disease. Treatment remains unsatisfactory. Here we evaluate the efficacy, safety, and pharmacokinetics of a single dose of the soluble guanylate cyclase stimulator riociguat in RP.

Self-gated mid-infrared short pulse upconversion detection for gas sensing.

Pulsed nonlinear-optical upconversion is used for mid-infrared signal detection. A setup for both mid-infrared generation and upconversion based on a single pump laser enables sensitive light detection and is utilized for gas spectroscopy. With the demonstrated pulsed setup, quantum efficiencies above 80 % for the upconversion of a Gaussian beam signal and 25 % for the upconversion of backscattered radiation are achieved and in agreement with theoretical predictions.

Upconversion-enabled array spectrometer for the mid-infrared, featuring kilohertz spectra acquisition rates.

Mid-infrared spectroscopy is an essential analytical method in science and industry. Unlike in the near-infrared range, grating spectrometers for the mid-infrared are rarely employed, mostly due to the limited availability and performance of suitable line array detectors. In this work, continuous-wave nonlinear-optical upconversion is used to enable mid-infrared spectroscopy.

Assessment of hearing aid algorithms using a master hearing aid: the influence of hearing aid experience on the relationship between speech recognition and cognitive capacity.

Objectives: Model-based hearing aid development considers the assessment of speech recognition using a master hearing aid (MHA). It is known that aided speech recognition in noise is related to cognitive factors such as working memory capacity (WMC). This relationship might be mediated by hearing aid experience (HAE).

Comparison of single-microphone noise reduction schemes: can hearing impaired listeners tell the difference?

Objective: The perceived qualities of nine different single-microphone noise reduction (SMNR) algorithms were to be evaluated and compared in subjective listening tests with normal hearing and hearing impaired (HI) listeners.

Design: Speech samples added with traffic noise or with party noise were processed by the SMNR algorithms. Subjects rated the amount of speech distortions, intrusiveness of background noise, listening effort and overall quality, using a simplified MUSHRA (ITU-R, 2003 ) assessment method.

Functionality of hearing aids: state-of-the-art and future model-based solutions.

A review about technical and perceptual factors in hearing aid technology, research and development is provided, covering current commercial solutions, underlying models of hearing loss for usage in hearing devices and emerging future technical solutions for hearing aid functionalities. A chain of techniques has provided incremental, but steady increases in user benefit, e.g.

Traumatic Frontal Epidural Hematoma Caused by Multiple Arterial Injuries in the Anterior Fossa.

Background: This case report illustrates the need to evaluate the possibility of multiple arterial sources when presented with a frontal epidural hematoma associated with facial trauma.

Case Description: The patient presented after being struck in the face by a baseball. Computed tomography of the brain revealed a large frontal epidural hematoma.

Iodine Migration and its Effect on Hysteresis in Perovskite Solar Cells.

The migration and accumulation of iodide ions create a modulation of the respective interfacial barriers causing the hysteresis in solar cells based on methylammonium lead iodide perovskites. Iodide ions are identified as the migrating species by measuring temperature dependent current-transients and photoelectron spectroscopy. The involved changes in the built-in potential due to ion migration are directly measured by electroabsorption spectroscopy.

Hearing aid fitting in older persons with hearing impairment: the influence of cognitive function, age, and hearing loss on hearing aid benefit.

Purpose: To examine the association of cognitive function, age, and hearing loss with clinically assessed hearing aid benefit in older hearing-impaired persons.

Methods: Hearing aid benefit was assessed using objective measures regarding speech recognition in quiet and noisy environments as well as a subjective measure reflecting everyday situations captured using a standardized questionnaire. A broad range of general cognitive functions such as attention, memory, and intelligence were determined using different neuropsychological tests.