Relationship quality and family formation in Europe.

The increase in cohabitation and nonmarital childbearing across Europe has raised questions about who still marries either before or after having a child. Although prior studies have addressed the sequence of marriage and childbearing, few have examined the role of relationship quality in these transitions. Here we employ a cross-national perspective to study the association between relationship quality and marriage and/or first birth within cohabitation.

First union formation among the children of immigrants: A population-wide study in Norway.

Using Norwegian register data on the total population of individuals who were native-born or who immigrated prior to age 18, this study investigated differences in first union formation across migrant generations, global regions of origin, and gender. Cohabitation was the preferred route into partnerships for all groups, but it was most common among those with either one or two native-born parents. Results provided evidence of a generational gradient in marriage, whereby the native-born children of two immigrants and those immigrating in ages below 13 were less likely to marry than immigrants arriving as teens.

Removing Fluoride-Terminations from Multilayered VC MXene by Gas Hydrolyzation.

Two-dimensional MXenes have shown great promise for many different applications, but in order to fully utilize their potential, control of their termination groups is essential. Here we demonstrate hydrolyzation with a continuous gas flow as a method to remove F-terminations from multilayered VC particles, in order to prepare nearly F-free and partly bare vanadium carbide MXene. Density functional theory calculations demonstrate that the substitution of F-terminations is thermodynamically feasible and presents partly nonterminated VCO as the dominating hydrolyzation product.

Unimolecular Decomposition Reactions of Picric Acid and Its Methylated Derivatives─A DFT Study.

To handle energetic materials safely, it is important to have knowledge about their sensitivity. Density functional theory (DFT) has proven a valuable tool in the study of energetic materials, and in the current work, DFT is employed to study the thermal unimolecular decomposition of 2,4,6-trinitrophenol (picric acid, PA), 3-methyl-2,4,6-trinitrophenol (methyl picric acid, mPA), and 3,5-dimethyl-2,4,6-trinitrophenol (dimethyl picric acid, dmPA). These compounds have similar molecular structures, but according to the literature, mPA is far less sensitive to impact than the other two compounds.

Performance Study of MXene/Carbon Nanotube Composites for Current Collector- and Binder-Free Mg-S Batteries.

The realization of sustainable and cheap Mg-S batteries depends on significant improvements in cycling stability. Building on the immense research on cathode optimization from Li-S batteries, for the first time a beneficial role of MXenes for Mg-S batteries is reported. Through a facile, low-temperature vacuum-filtration technique, several novel current collector- and binder-free cathode films were developed, with either dipenthamethylene thiuram tetrasulfide (PMTT) or S nanoparticles as the source of redox-active sulfur.