Functional interfaces between electronics and biological matter are essential to diverse fields including health sciences and bio-engineering. Here, we report the discovery of spontaneous (no external energy input) hydrogen transfer from biological glucose reactions into SmNiO, an archetypal perovskite quantum material. The enzymatic oxidation of glucose is monitored down to ~5 × 10 M concentration via hydrogen transfer to the nickelate lattice.
View Article and Find Full Text PDFDesigning materials to function in harsh environments, such as conductive aqueous media, is a problem of broad interest to a range of technologies, including energy, ocean monitoring and biological applications. The main challenge is to retain the stability and morphology of the material as it interacts dynamically with the surrounding environment. Materials that respond to mild stimuli through collective phase transitions and amplify signals could open up new avenues for sensing.
View Article and Find Full Text PDFFuel cells convert chemical energy directly into electrical energy with high efficiencies and environmental benefits, as compared with traditional heat engines. Yttria-stabilized zirconia is perhaps the material with the most potential as an electrolyte in solid oxide fuel cells (SOFCs), owing to its stability and near-unity ionic transference number. Although there exist materials with superior ionic conductivity, they are often limited by their ability to suppress electronic leakage when exposed to the reducing environment at the fuel interface.
View Article and Find Full Text PDFAims And Objectives: The aims and objectives of our study were to compare four sequential overlays generated using the envelopment technique and to evaluate inter- and intraoperator reliability of the overlays obtained by the envelopment technique.
Materials And Methods: Dental stone models were prepared from impressions made from healthy individuals; photographs were taken and computer-assisted overlays were generated. The models were then enveloped in a different-color dental stone.