Publications by authors named "K Manna"

Drug delivery vehicles optimize therapeutic outcomes by enhancing drug efficacy, minimizing side effects, and providing controlled release. Injectable hydrogels supersede conventional ones in the field of drug delivery owing to their less invasive administration and improved targeting. However, they face challenges such as low biodegradability and biocompatibility, potentially compromising their effectiveness.

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The direct transformation of methane into C oxygenates such as acetic acid selectively using molecular oxygen (O) is a significant challenge due to the chemical inertness of methane, the difficulty of methane C-H bond activation/C-C bond coupling and the thermodynamically favored over-oxidation. In this study, we have successfully developed a porous aluminium metal-organic framework (MOF)-supported single-site mono-copper(ii) hydroxyl catalyst [MIL-53(Al)-Cu(OH)], which is efficient in directly oxidizing methane to acetic acid in water at 175 °C with a remarkable selectivity using only O. This heterogeneous catalyst achieved an exceptional acetic acid productivity of 11 796 mmol mol h in 9.

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The emerging field of orbitronics aims to generate and control orbital angular momentum for information processing. Chiral crystals are promising orbitronic materials because they have been predicted to host monopole-like orbital textures, where the orbital angular momentum aligns isotropically with the electron's crystal momentum. However, such monopoles have not yet been directly observed in chiral crystals.

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Colossal magnetoresistance (CMR) is an exotic phenomenon that allows for the efficient magnetic control of electrical resistivity and has attracted significant attention in condensed matter due to its potential for memory and spintronic applications. Heusler alloys are the subject of considerable interest in this context due to the electronic properties that result from the nontrivial band topology. Here, the observation of CMR near room temperature is reported in the shape memory Heusler alloy NiMnIn, which is attributed to the combined effects of magnetic field-induced martensite twin variant reorientation (MFIR) and magnetic field-induced structural phase transformation (MFIPT).

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Article Synopsis
  • Direct oxidation of methane to valuable products like alcohols and acetic acid is challenging due to strong C-H bonds and the risk of overoxidation to CO.
  • The study presents a new catalytic system using a multifunctional iron(III) dihydroxyl species within a metal-organic framework (MOF) to achieve selective oxidation of methane.
  • Experimental and theoretical findings indicate that methanol and acetic acid are produced through distinct mechanisms, including a catalytic cycle and specific coupling reactions.
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