Publications by authors named "K I Carnes"

Article Synopsis
  • - The study investigates how bromoform (CHBr) behaves when exposed to near-infrared (NIR) light, focusing on its breakdown and isomerization in cationic states through advanced imaging techniques.
  • - It is observed that the dissociation process, particularly when forming HBr and Br fragments, occurs with a delay compared to the faster breakdown of the C-Br bond.
  • - Molecular dynamics simulations indicate that this delay results from temporary isomerization processes involving H- and Br-migrations before the final fragments are produced.
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We have measured the photodissociation of few-keV OD molecular ions into either D + O or O + D final products. The three-dimensional momentum imaging measurements of the light and massive fragments in coincidence were enabled by using an upgraded two-detector setup. In this work, we show that absorption of a single 790 or 395 nm photon excites the OD from its electronic ground state to the B state, which dissociates to the O(S) + D dissociation limit.

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An essential problem in photochemistry is understanding the coupling of electronic and nuclear dynamics in molecules, which manifests in processes such as hydrogen migration. Measurements of hydrogen migration in molecules that have more than two equivalent hydrogen sites, however, produce data that is difficult to compare with calculations because the initial hydrogen site is unknown. We demonstrate that coincidence ion-imaging measurements of a few deuterium-tagged isotopologues of ethanol can determine the contribution of each initial-site composition to hydrogen-rich fragments following strong-field double ionization.

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Introduction: Medicaid, a joint federal-state program, finances health care for eligible low-income individuals and families in the United States. Medicaid patients use disproportionately more emergency room (ER) services than other patients in the United States. Inadequate provider communication during primary care visits might be one reason for this well-documented phenomenon.

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Importance: Postoperative opioid prescriptions are associated with delayed recovery, perioperative complications, opioid use disorder, and diversion of overprescribed opioids, which places the community at risk of opioid misuse or addiction.

Objective: To assess a protocol for eliminating postdischarge opioid prescriptions after major urologic cancer surgery.

Design, Setting, And Participants: This cohort study of the no opioid prescriptions at discharge after surgery (NOPIOIDS) protocol was conducted between May 2017 and June 2021 at a tertiary referral center.

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