Two-dimensional (2D) nanostructured liquid crystals containing fluorinated cyclohexylphenyl and cyclic carbonate moieties have been developed as quasi-solid-state self-organized electrolytes for safe lithium-ion batteries. We have designed lithium ion-conductive liquid-crystalline (LC) materials with fluorine substituents on mesogens for improved oxidation stability. Computational studies suggest that the fluorination of mesogens lowers the highest occupied molecular orbital (HOMO) level of LC molecules and improves their oxidation resistance as electrolytes.
View Article and Find Full Text PDFThe nuptial flight of ants usually occurs during certain periods of the year. Alate females and males fly out of their nests to mate simultaneously. In the genus Camponotus, sex-specific chemicals are deposited in the male head; however, their roles in nuptial flight have not yet been clarified.
View Article and Find Full Text PDFObjective: Tracheoesophageal puncture (TEP) is one of the most established methods for voice reacquisition following total laryngectomy. The most difficult complication following TEP is the management of saliva leakage or secretion into the trachea due to TE fistula enlargement. In this study, we devised a new strategy to close TE fistulas and confirmed its safety and effectiveness.
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