Publications by authors named "K B Foreman"

Article Synopsis
  • - A study using anion photoelectron spectroscopy and computational methods investigated the photodetachment of UF, revealing a vertical detachment energy of 0.63 eV, aligning closely with a theoretical value of 0.61 eV from spinor-based relativistic coupled-cluster methods.
  • - The analysis included complex spectral features related to excited electronic states and vibrational movements in UF, facilitated by advanced theoretical techniques like spin-orbit-coupled multireference perturbation theory.
  • - The research confirms that UF exhibits strong ionic bonding characteristics and showcases the effectiveness of the spinor CCSD(T) computational approach in analyzing such systems.
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Background: Individuals with transhumeral limb loss have an increased risk of falling, potentially resulting from altered upper-body kinematics during gait. The purpose of this study was to investigate whole-body angular momentum as a measure of movement control, to gain an understanding of how these upper-body kinematics contribute to dynamic balance.

Methods: Eight participants with transhumeral limb loss and eight able-bodied control participants completed three gait trials at self-selected speeds.

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Introduction: Transthoracic (TTE) follow up guidelines after PFO device closure are vague. The primary goal of this study was to perform a literature search to characterize the timing of complications that occur after PFO device placement to determine the utility of long-term routine TTE.

Methods: A search was performed in Medline (PubMed) with English language and publication date (2000-2023) filters were applied.

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Chemical weapons, including hyper lethal nerve agents, are a persistently looming threat across the modern geopolitical landscape. There is a pressing need for the design and development of improved protective materials, which can be substantially aided by the cultivation of a fundamental molecular-level understanding of candidate systems and the corresponding decomposition chemistry. The emergence of the exciting new class of single atom catalyst (SAC) materials has enhanced the prospect of subnanoscale design tailoring in the hopes of optimizing activity and selectivity for a variety of chemical applications.

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Anion photoelectron spectra of ThSO- and ThS2- were recorded using the third (355 nm) harmonic of an Nd-YAG laser; these provided the measured vertical detachment energies of each anion. The experiments are supported by extensive coupled cluster calculations on ThSO, ThSO-, ThS2, and ThS2-, as well as the oxygen congeners ThO2 and ThO2-. The ab initio calculations, which included complete basis set extrapolations, spin-orbit effects using four-component coupled cluster, and higher-order correlation contributions through CCSDT(Q), yielded an adiabatic electron affinity for ThO2 that was within 0.

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