The present study investigates the potential of skin-derived carbon nanospheres (CNSs) as an efficient adsorbent for the rapid removal of cationic dyes from aqueous solutions. The CNSs were synthesized through a facile, cost-effective, catalyst-free and environmentally friendly process, utilizing skin waste as a precursor. This is the first reported study on the synthesis of mesoporous carbon nanospheres from skin.
View Article and Find Full Text PDFMagnetic nanoparticle-incorporated metal organic frameworks (MOF) are potential composites for various applications such as catalysis, water treatment, drug delivery, gas storage, chemical sensing, and heavy metal ion removal. MOFs exhibits high porosity and flexibility enabling guest species like heavy metal ions to diffuse into bulk structure. Additionally, shape and size of the pores contribute to selectivity of the guest materials.
View Article and Find Full Text PDFNovel porous nanospheres from areca nuts (ACNPs) were synthesized via one-step pyrolysis without the use of any chemical treatment and the materials were used as adsorbents for the removal of cationic methylene blue (MB) and anionic methyl orange (MO) as well as their binary mixtures. Around, 6-7 tonnes of areca nut biowaste is generated every year which are then burnt due to their slow rate of decomposition resulting in higher carbon footprints. Biosorbents are generally a preferable alternative for dye adsorption but involve chemical modification for surface enhancement and complex sample treatment.
View Article and Find Full Text PDFDespite the advantages of high contaminant removal, operational flexibility, and technical advancements offered, the undesirable fouling property of membranes limits their durability, thus posing restrictions on their usage. An enormous struggle is underway to conquer this major challenge. Most of the earlier reviews include the basic concepts of fouling and antifouling, with respect to particular separation processes such as ultrafiltration, nanofiltration, reverse osmosis and membrane bioreactors, graphene-based membranes, zwitterionic membranes, and so on.
View Article and Find Full Text PDFPerovskite quantum dots (PQDs) offer high photoluminescence quantum yields; however, due to their limited stability in aqueous media, to date their utilization in biomedical applications has been limited. The present work demonstrates highly fluorescent and stable aqueous PQDs that were synthesized using a facile engineered phase transfer method. Ligands were engineered to have a dual functionality, i.
View Article and Find Full Text PDFIn the present study, recyclable porous nano-carbons (PNCs) were used to remove textile dyes (mainly methylene blue, methyl orange, and rhodamine B) from an aqueous environment. Due to their high surface area and mesoporous nature, PNCs exhibited extremely fast and efficient adsorption behavior. PNCs synthesized at an elevated temperature of 1000 °C are used in batch experiments, as they showed maximum dye removal with high surface area.
View Article and Find Full Text PDFBiowaste based nanoadsorbents have gained much attention in the recent times for wastewater decolourization owing to their low cost, high surface area and high adsorption capacities. In the present research, garlic peel based nanoparticles (GCNP) were synthesized at different temperatures by a one step pyrolytic green approach for the effective removal of cationic dye, malachite green from the aqueous medium. The surface properties of Garlic nanoparticles were elucidated by N adsorption- desorption and all the GCNP samples were found to exhibit Type IV(a) isotherm indicating the presence of mesopores in carbon matrix.
View Article and Find Full Text PDFHerein we present a new approach for the complete removal of Cr(VI) species, through reduction of Cr(VI) to Cr(III), followed by adsorption of Cr(III). Reduction of chromium from water is an important challenge, as Cr(IV) is one of the most toxic substances emitted from industrial processes. Chitosan (CS) thin films were developed on plain polysulfone (PSf) and PSf/TiO2 membrane substrates by a temperature-induced technique using polyvinyl alcohol as a binder.
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