Novel core-shell materials SiO@Tb-MOF for the incorporation of spiropyran molecules and its application in dynamic advanced information encryption.

Dynamic fluorescent switches with multiple light outputs offer promising opportunities for advanced security encryption. However, the achievement of dynamic emission, particularly when based on the timing of external stimuli, continues to present a significant challenge. Herein, a unique dynamic fluorescent switch was developed by integrating spiropyran molecules (SP) into a core-shell structure (SiO@Tb-MOF).

Improved interfacial compatibility between unsaturated polyester resin and rice straw fibers after non-washing treatment with Ca(OH).

The agricultural industry produces a substantial volume of rice straw (RS) annually, highlighting the importance of recycling RS for sustainable materials. However, the poor interfacial compatibility between RS and polymers often leads to drawbacks in their composites, such as water-swelling and limited tensile strength. Here, we propose a novel approach using Ca(OH) that offers several distinct advantages: enhancement of interfacial compatibility, elimination of the need for water washing, and formation of calcified hybrid particles on fiber surfaces by capturing CO from the atmosphere.

Structural Colored Fabric Based on Monodisperse CuO Microspheres.

Structural-colored fabrics have been attracting much attention due to their eco-friendliness, dyelessness, and anti-fading properties. Monodisperse microspheres of metal, metal oxide, and semiconductors are promising materials for creating photonic crystals and structural colors owing to their high refractive indices. Herein, CuO microspheres were prepared by a two-step reduction method at room temperature; the size of CuO microspheres was controlled by changing the molar ratio of citrate to Cu; and the size of CuO microspheres was tuned from 275 nm to 190 nm.

Utilization of deep eutectic solvent as a degumming protocol for raw silk: Towards performance and mechanism elucidation.

Degumming is the most critical step for the silk textile industry and the process of silk-based advanced materials. However, current common degumming techniques are largely limited because of insufficient efficiency, obvious hydrolysis damage and difficulty in long-term storage. Here, deep eutectic solvent (DES) constituted of choline chloride (ChCl) and urea was explored to Bombyx mori silk fibers degumming without combining any further treatment.