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View Article and Find Full Text PDFPolycarboxylate ether (PCE) with different main chain structures was prepared by aqueous solution free radical polymerization using unsaturated acids containing sulfonic acid groups, acrylamide groups, and carboxyl groups and isoprenyl polyoxyethylene ether (IPEG). The molecular structure was characterized by infrared spectroscopy and gel chromatography, while adsorption, dispersion, and hydration properties were studied using a total organic carbon analyzer, rheometer, and isothermal microcalorimeter, respectively. The results show that the adsorption process of PCE on cement particles is spontaneous physical adsorption.
View Article and Find Full Text PDFThis study synthesized polycarboxylate superplasticizer (PCE) with varying carboxyl densities and main chain degrees of polymerization. The structural parameters of PCE were characterized using gel permeation chromatography and infrared spectroscopy. The study investigated the impact of PCE's diverse microstructures on cement slurry's adsorption, rheology, hydration heat, and kinetics.
View Article and Find Full Text PDFTo investigate the effects of Reference cement (RC) and Belite cement (LC) systems, different molecular structures of polycarboxylate ether (PCE) were prepared through the free radical polymerization reaction and designated as PC-1 and PC-2. The PCE was characterized and tested using a particle charge detector, gel permeation chromatography, a rotational rheometer, a total organic carbon analyzer, and scanning electron microscopy. The results showed that compared to PC-2, PC-1 exhibited higher charge density and better molecular structure extension, with smaller side-chain molecular weight and molecular volume.
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