Single-Atom Metallophilic Sites for Liquid NaK Alloy Confinement toward Stable Alkali-Metal Anodes.

Room temperature liquid NaK alloy is a promising candidate for high performance metal batteries, due to its dendrite-free property and high energy density. However, its practical application is hindered by the high surface tension of liquid NaK, which causes difficulties in maintaining a stable contact with a current collector. Here, the authors demonstrate the extraordinary stable confinement of NaK alloy at room temperature by constructing a super-wetting substrate, which is based on highly dispersed cobalt-single-atom carbon nanoarrays.

Confinement of Zinc Salt in Ultrathin Heterogeneous Film to Stabilize Zinc Metal Anode.

Aqueous zinc metal batteries (AZMBs) have drawn great attention due to the high theoretical capacity, low redox potential, and abundance reserves. However, the practical application of rechargeable AZMBs are hindered by the poor reversibility of Zn metal anode, owing to easy dendrite growth and serious side reactions. Herein, the preparation of heterogeneous interfacial film with highly dispersed and confined zinc salt in a 2D channel by coassembling polyamide 6, zinc trifluoromethanesulfonate, and layered double hydroxides, which significantly suppresses the dendrite formation, H evolution reaction as well as O corrosion is reported.

A bifunctional nonenzymatic flexible glucose microsensor based on CoFe-Layered double hydroxide.

A bifunctional flexible glucose microsensor has been successfully fabricated by directly growing a layered double hydroxide nanosheet array (LDH-NSA) on Ni wire. The as-obtained CoFe-LDH-NSA exhibits promising performances in electrochemical and colorimetric detection of glucose with high sensitivity and selectivity. This work demonstrates an effective strategy to fabricate multi-functional glucose nonenzyme sensors.

Electrosynthesis of Well-Defined Metal-Organic Framework Films and the Carbon Nanotube Network Derived from Them toward Electrocatalytic Applications.

An efficient and controllable method to synthesize continuous metal-organic framework (MOF) films is highly desired. Herein, we demonstrate a facile and universal electrochemical method to synthesize homogeneous and uniform zeolitic imidazolate framework (ZIF, a typical class of MOF family) films on various macroconductive substrates (e.g.