We describe the design and performance evaluation of a portable gas chromatograph suitable for the analysis of volatile organic and odorous compounds at trace levels. The system comprises a carbon nanotube sponge preconcentrator, an electronic pressure control (EPC) unit, a temperature-programmable column module, and a fast-response photoionization detector. A built-in tablet computer controls instrumental parameters and chromatogram display functions.
View Article and Find Full Text PDFSensitive methods are required for in situ monitoring of volatile organic compounds (VOCs). Herein, carbon nanotube (CNT) sponges were investigated as a new type of adsorbent for enriching trace aromatic VOCs. A square pillar configuration (3 mm × 3 mm × 45 mm, 5 mg) of a CNT sponge was enclosed in a glass tube (4 mm i.
View Article and Find Full Text PDFA carbon nanotube (CNT) sponge was synthesized and examined as an adsorptive material for a thermally desorbed preconcentrator for volatile organic compounds (VOCs). The porous sponge-like material, retaining the intrinsic properties of individual multiwalled (MW) CNTs, was fabricated using spray pyrolysis chemical vapor deposition (CVD). The square pillar form of the CNT sponge was enclosed in a 1/4″ glass tube with fittings for flow-through sampling.
View Article and Find Full Text PDFThis study mainly evaluated the effectiveness of ozonation toward the enhancement of the removal efficiencies of antibiotic-resistant bacteria (ARB), pB10 plasmid transfer, and pB10 plasmids under different pH and suspended solids (SS) and humic acid concentrations. First, chlorination was tested as a reference disinfection process. Chlorination at a very high dose concentration of Cl2 (75 mg L(-1)) and a long contact time (10 min) were required to achieve approximately 90% ARB and pB10 plasmid transfer removal efficiencies.
View Article and Find Full Text PDFThis study compared three different disinfection processes (chlorination, E-beam, and ozone) and the efficacy of three oxidants (H2O2, S2O(-)8, and peroxymonosulfate (MPS)) in removing antibiotic resistant bacteria (ARB) and antibiotic resistance genes (ARGs) in a synthetic wastewater. More than 30 mg/L of chlorine was needed to remove over 90% of ARB and ARG. For the E-beam method, only 1 dose (kGy) was needed to remove ARB and ARG, and ozone could reduce ARB and ARG by more than 90% even at 3 mg/L ozone concentration.
View Article and Find Full Text PDFThe presence of antibiotics in the natural environment has been a growing issue. This presence could also account for the influence that affects microorganisms in such a way that they develop resistance against these antibiotics. The aim of this study was to evaluate whether the antibiotic resistant gene (ARG) plasmid transfer can be facilitated by the impact of 1) environmentally representative micro-contaminant concentrations in ppb (part per billion) levels and 2) donor-recipient microbial complexity (pure vs.
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