Unraveling the Mechanism and Practical Implications of the Sol-Gel Synthesis of Spinel LiMnO as a Cathode Material for Li-Ion Batteries: Critical Effects of Cation Distribution at the Matrix Level.

Spinel LiMnO (LMO) is a state-of-the-art cathode material for Li-ion batteries. However, the operating voltage and battery life of spinel LMO needs to be improved for application in various modern technologies. Modifying the composition of the spinel LMO material alters its electronic structure, thereby increasing its operating voltage.

Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries.

Sn is a promising candidate anode material with a high theoretical capacity (994 mAh/g). However, the drastic structural changes of Sn particles caused by their pulverization and aggregation during charge-discharge cycling reduce their capacity over time. To overcome this, a TiNi shape memory alloy (SMA) was introduced as a buffer matrix.

High Electrochemical Performance Silicon Thin-Film Free-Standing Electrodes Based on Buckypaper for Flexible Lithium-Ion Batteries.

Recently, applications for lithium-ion batteries (LIBs) have expanded to include electric vehicles and electric energy storage systems, extending beyond power sources for portable electronic devices. The power sources of these flexible electronic devices require the creation of thin, light, and flexible power supply devices such as flexile electrolytes/insulators, electrode materials, current collectors, and batteries that play an important role in packaging. Demand will require the progress of modern electrode materials with high capacity, rate capability, cycle stability, electrical conductivity, and mechanical flexibility for the time to come.

Experimental Study on Characteristics of Grinded Graphene Nanofluids with Surfactants.

In earlier studies, much research has focused on increasing the efficiency of heat exchanger fields. Therefore, in this study, graphene nanofluid was fabricated for use as a heat transfer medium for a heat exchanger. Graphene has excellent electrical conductivity, mechanical properties, and heat transfer properties.

Electrochemical properties of Si film electrodes grown on current collectors with CuO nanostructures for thin-film microbatteries.

Si film electrodes were deposited onto Cu foil current collectors fabricated with well-formed CuO nanostructures. The structural and electrochemical properties of the Cu foils oxidized for 1, 3, and 6 h and of the Si film electrodes were investigated using field-emission scanning electron microscopy, X-ray diffraction (XRD), and charge/discharge tests. The morphologies and XRD profiles suggested that the oxidized Cu foils consisted of a top CuO layer and a bottom Cu2O layer.

Compositionally graded Ti-Ni alloys prepared by diffusion bonding.

A Ti-Ni alloy compositionally graded along the thickness direction in order to obtain a shape change over a wide temperature range, which is beneficial to the actuator for precise position control, was prepared by spark plasma sintering (SPS) after stacking Ti-Ni alloy ribbons in the sequence of Ti-51Ni, Ti-50Ni, Ti-49Ni and Ti-48Ni (at%) followed by annealing. Then, the microstructure and martensitic transformation behavior were investigated by using FE-SEM, DSC and thermal cycling tests under a constant load. The inter-ribbon defects observed after SPS due to insufficient diffusional bonding between the ribbons were eliminated by post-SPS annealing at 1023 K for 36 ks.

Protection effect of ZrO2 coating layer on LiCoO2 thin film fabricated by DC magnetron sputtering.

Bare and ZrO2-coated LiCoO2 thin films were fabricated by direct current magnetron sputtering method on STS304 substrates. Deposited both films have a well-crystallized structure with (003) preferred orientation after annealing at 600 degrees C. The ZrO2-coated LiCoO2 thin film provide significantly improved cycling stability compared to bare LiCoO2 thin film at high cut-off potential (3.

Influences of Ti film thickness on electrochemical properties of Si/Ti/Cu film electrodes.

Si and Si/Ti films were fabricated on a Cu current collector (substrate) using the DC sputtering system. The Ti film as a buffer layer was inserted between the Si film and the Cu current collector. Their structural and electrochemical properties were investigated with various Ti film thicknesses of 20-90 nm.

The effects of substrate and annealing on structural and electrochemical properties in LiCoO2 thin films prepared by DC magnetron sputtering.

LiCoO2 thin films were fabricated by direct current magnetron sputtering method on STS304 and Ti substrates. The effects of substrate and annealing on their structural and electrochemical properties of LiCoO2 thin film cathode were studied. Crystal structures and surface morphologies of the deposited films were investigated by X-ray diffraction and field emission scanning electron microscopy.

Patterned Si thin film electrodes for enhancing structural stability.

A patterned film (electrode) with lozenge-shaped Si tiles could be successfully fabricated by masking with an expanded metal foil during film deposition. Its electrochemical properties and structural stability during the charge-discharge process were examined and compared with those of a continuous (conventional) film electrode. The patterned electrode exhibited a remarkably improved cycleability (75% capacity retention after 120 cycles) and an enhanced structural stability compared to the continuous electrode.