The silicon nanostructure is a promising candidate for an anode of Li-ion batteries due to its high theoretical capacity. In this work, we have demonstrated the scalable synthesis of Si nanosheets from natural sand by magnesiothermic reduction, and suggested a new formation mechanism for Si nanosheets. In the suggested mechanism, an Mg₂Si intermediate phase was formed at an early stage of the reduction process, which leads to the two-dimensional Si nanostructure.
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