To develop highly efficient thermoelectric materials, the generation of homogeneous heterostructures in a matrix is considered to mitigate the interdependency of the thermoelectric compartments. In this study, CuTe nanoparticles were introduced onto BiTeSe n-type materials and their thermoelectric properties were investigated in terms of the amount of CuTe nanoparticles. A homogeneous dispersion of CuTe nanoparticles was obtained up to 0.
View Article and Find Full Text PDFNanostructuring is considered one of the key approaches to achieve highly efficient thermoelectric alloys by reducing thermal conductivity. In this study, we investigated the effect of oxide (ZnO and SnO) nanolayers at the grain boundaries of polycrystalline InYbCoSb skutterudites on their electrical and thermal transport properties. Skutterudite powders with oxide nanolayers were prepared by atomic layer deposition method, and the number of deposition cycles was varied to control the coating thickness.
View Article and Find Full Text PDFAu@Ag core-shell structures have received particular interest due to their localized surface plasmon resonance properties and great potential as oxygen reduction reaction catalysts and building blocks for self-assembly. In this study, Au@Ag core-shell nanocubes (Au@AgNCs) were fabricated in a facile manner stepwise Ag reduction on Au nanoparticles (AuNPs). The size of the Au@AgNCs and their optical properties can be simply modulated by changing the Ag shell thickness.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
September 2012
The title compound C(20)H(20)O(4)S, is polymorphic. In the tetra-gonal form, the mol-ecule lies on a crystallographic twofold axis, while the monoclinic form has only approximate C(2) mol-ecular symmetry. The greatest excursion from C(2) symmetry is in the orientation of the two phenyl rings; at 100 K, one of the rings is rotated -37.
View Article and Find Full Text PDFSingle crystals of Ln(Cu,Al)12 and Ln(Cu,Ga)12 compounds (Ln = Y, Ce-Nd, Sm, Gd-Ho, and Yb for Al and Ln = Y, Gd-Er, Yb for Ga) have been grown by flux-growth methods and characterized by means of single-crystal x-ray diffraction, complemented with microprobe analysis, magnetic susceptibility, resistivity and heat capacity measurements. Ln(Cu,Ga)12 and Ln(Cu,Al)12 of the ThMn12 structure type crystallize in the tetragonal I4/mmm space group with lattice parameters a approximately 8.59 Å and c approximately 5.
View Article and Find Full Text PDFSingle crystals of SmCu4Ga8 have been grown using Ga flux and characterized by single-crystal X-ray diffraction. SmCu4Ga8, isostructural to SmZn11, crystallizes in the hexagonal P6/mmm (No. 191) space group, with Z = 3 and lattice parameters a = 8.
View Article and Find Full Text PDFJ Phys Condens Matter
July 2007
Single crystals of Ln(4)MGa(12) (Ln = Dy, Ho, Er; M = Pd,Pt) were synthesized by a flux technique using excess Ga and characterized by single crystal x-ray diffraction. Ln(4)MGa(12) (Ln = Dy, Ho, Er; M = Pd,Pt) crystallize in the cubic space group [Formula: see text] (no. 229) with lattice parameter a∼8.
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