Angew Chem Int Ed Engl
July 2024
The electrochemical nitrate reduction reaction (NORR) is able to convert nitrate (NO ) into reusable ammonia (NH), offering a green treatment and resource utilization strategy of nitrate wastewater and ammonia synthesis. The conversion of NO to NH undergoes water dissociation to generate active hydrogen atoms and nitrogen-containing intermediates hydrogenation tandemly. The two relay processes compete for the same active sites, especially under pH-neutral condition, resulting in the suboptimal efficiency and selectivity in the electrosynthesis of NH from NO .
View Article and Find Full Text PDFSeawater is one of the most important CO sequestration media for delivering value-added chemicals/fuels and active chlorine; however, this scenario is plagued by sluggish reaction rates and poor product selectivity. Herein, we first report the synthesis of nitrogen-doped BiOCl atomic layers to directly split carbon-sequestrated natural seawater (Yellow Sea, China) into stoichiometric CO (92.8 μmol h ) and HClO (83.
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