Dynamic multicolor emissions of multimodal phosphors by Mn trace doping in self-activated CaGaO.

The manipulation of excitation modes and resultant emission colors in luminescent materials holds pivotal importance for encrypting information in anti-counterfeiting applications. Despite considerable achievements in multimodal and multicolor luminescent materials, existing options generally suffer from static monocolor emission under fixed external stimulation, rendering them vulnerability to replication. Achieving dynamic multimodal luminescence within a single material presents a promising yet challenging solution.

Senescent skeletal cells cross-talk with synovial cells plays a key role in the pathogenesis of osteoarthritis.

Osteoarthritis (OA) has been recognized as an age-related degenerative disease commonly seen in the elderly that affects the whole "organ" including cartilage, subchondral bone, synovium, and muscles. An increasing number of studies have suggested that the accumulation of senescent cells triggering by various stresses in the local joint contributes to the pathogenesis of age-related diseases including OA. In this review, we mainly focus on the role of the senescent skeletal cells (chondrocytes, osteoblasts, osteoclasts, osteocyte, and muscle cells) in initiating the development and progression of OA alone or through cross-talk with the macrophages/synovial cells.

Short-Term Non-Decaying Mechanoluminescence in LiMgGeO:Mn.

Trap-controlled mechanoluminescent (ML) materials characterized by reproducible mechanoluminescence (ML) after irradiation recharging have shown attractive prospects in applications including stress distribution visualization, stress-driven light sources, and anti-counterfeiting. However, these materials generally suffer from the difficulty of achieving non-decaying ML when subjected to continuous mechanical stimulation. Herein, we develop a trap-controlled reproducible ML material, LiMgGeO:Mn, and report its short-term non-decaying ML behavior.

Expression response of chalcone synthase gene to inducing conditions and its effect on flavonoids accumulation in two medicinal species of Anoectochilus.

Anoectochilus roxburghii and Anoectochilus formasanus are the major species of genus Anoectochilus used in traditional Chinese medicine for their abundant content of flavonoids and some other medicinal constituents. In recent years, their wild resources are gradually exhausted due to over-collection and ecological deterioration. Artificial cultivation and tissue culture are employed to increase production.

Achieving Thermo-Mechano-Opto-Responsive Bitemporal Colorful Luminescence via Multiplexing of Dual Lanthanides in Piezoelectric Particles and its Multidimensional Anticounterfeiting.

Optical characteristics of luminescent materials, including emission color (wavelength), lifetime, and excitation mode, play crucial roles in data communication and information security. Conventional luminescent materials generally display unicolor, unitemporal, and unimodal (occasionally bimodal) emission, resulting in low-level readout and decoding. The development of multicolor, multitemporal, and multimodal luminescence in a single material has long been considered to be a significant challenge.

Ultrasensitive Fluorescence Lifetime Tuning in Patterned Polymer Composite Nanofibers with Plasmonic Nanostructures for Multiplexing.

Regulating fluorescence lifetime of lanthanide nanocomposites is highly desired for optical multiplexing applications, for instance, security printing, anticounterfeiting, and data storage. Herein, sensitive fluorescence lifetime tuning in nanocomposite fibers is reported which are composed of silica-coated gold nanorods assembled in Eu-polystyrene nanofibers. The prepared nanofibers possess unique properties of tunable fluorescence lifetime and distinct textured patterns together with superior flexibility and superhydrophobicity.

Giant spontaneous exchange bias obtained by tuning magnetic compensation in samarium ferrite single crystals.

Spontaneous exchange bias (SEB) under zero field cooling (ZFC) has recently attracted lots of attention due to its underlying physics and potential applications. Here we report the giant SEB (GSEB) of SmFeO single crystals by tuning magnetic compensation by temperature, which is rather convenient. A SEB field of up to 1 T at 3.

Piezoluminescence from ferroelectric CaTiO:Pr long-persistent phosphor.

A variety of up-and-coming applications of piezoluminescence in artificial skins, structural health diagnosis, and mechano-driven lightings and displays recently have triggered an intense research effort to design and develop new piezoluminescent materials. In this work, we deduced and verified an efficient piezoluminescence in ferroelectric CaTiO:Pr long-persistent phosphor, in view of three fundamental elements forming piezoluminescence - piezoelectricity, luminescent centers and carrier traps. Under the stimulation of mechanical actions including compression and friction, CaTiO:Pr shows an intense red emission from D-H transition of Pr.

AC Electroluminescent Processes in Pr-Activated (BaCa)TiO₃ Diphase Polycrystals.

We investigated the properties of alternating current (AC)-driven electroluminescence from (BaCa)TiO₃:Pr diphase polycrystal-based device. The results of crystal phases and micrographs, and the symmetrical dual emissions in one AC cycle, indicate the spontaneous formation of a dielectric/phosphor/dielectric sandwich microstructure in (BaCa)TiO₃:Pr. The electroluminescent device emits a red light of 617 nm, which is attributed to the ¹D₂-³H₄ transition of Pr in the phosphor phase.

Colorful Hydrophobic Poly(Vinyl Butyral)/Cationic Dye Fibrous Membranes via a Colored Solution Electrospinning Process.

Colorful nanofibrous membranes have attracted much attention for their visual varieties and various functionalities. In this article, a colored solution electrospinning process was used to fabricate colorful hydrophobic poly(vinyl butyral) (PVB)/cationic dye nanofibrous membranes (NFMs) successfully. The color and morphology of these as-spun nanofibrous membranes have been analyzed by colorimetry, spectroscopy, and scanning electron microscopy (SEM).

Multicolor Tuning in Room-Temperature Self-Activated Ca Nb O Submicroplates by Lanthanide Doping.

Self-activated phosphors are capable of generating optical emissions from the internal ion groups of host lattice before externally introducing luminescent ions. However, numerous self-activated phosphors only show luminescence at low temperature due to the thermally activated energy migration among ion groups at room temperature, severely confining their application conditions. In this letter, we propose a strategy to converting the low-temperature luminescence to a room-temperature one through changing the synthesis conditions to induce structural distortions and thus to limit energy migration.

Electrospun anisotropic architectures and porous structures for tissue engineering.

In order to design scaffolds for tissue engineering with proper architectures, organization and properties, a variety of materials and technologies are being developed. In addition to being biocompatible both in their bulk and degraded forms, scaffolds should not only possess appropriate mechanical properties to provide a suitable stress environment, but also be porous and permeable to permit the ingress of cells and nutrients. In this review, we aim to summarize recent advances in electrospun anisotropic architectures such as aligned fibrous arrays, fibrous yarns and bundles, fibrous tubular structures, and porous structures, as well as their formation mechanisms and mechanical properties.

Electrical transport properties of an isolated CdS microrope composed of twisted nanowires.

CdS is one of the important II-VI group semiconductors. In this paper, the electrical transport behavior of an individual CdS microrope composed of twisted nanowires is studied. It is found that the current-voltage (I-V) characteristics show two distinct power law regions from 360 down to 60 K.

Self-powered electrospinning apparatus based on a hand-operated Wimshurst generator.

A conventional electrospinning setup cannot work without a plug (electricity supply). In this article, we report a self-powered electrospinning setup based on a hand-operated Wimshurst generator. The new device has better applicability and portability than a typical conventional electrospinning setup because it is lightweight and can work without an external power supply.

Elastico-mechanoluminescence in CaZr(PO4)2:Eu2+ with multiple trap levels.

We report on a novel elastico-mechanoluminescence (EML) phosphor of CaZr(PO4)2:Eu2+ for simultaneous luminescent sensing and imaging to mechanical load by the light-emitting of Eu2+ ions. The EML properties of CaZr(PO4)2:Eu2+ show an intense luminance (above 15 mcd m(-2)), a low load threshold (below 5 N), a broad measurement range for the dynamic load (up to 2000 N), and an accurate linear relationship of EML intensity against the applied load. The excellent EML characteristics are considered to originate from the piezoelectric crystal structure and the multiple trap levels with appropriate depths.

An intense elastico-mechanoluminescence material CaZnOS:Mn2+ for sensing and imaging multiple mechanical stresses.

The elastico-mechanoluminescence (EML) properties of CaZnOS:Mn2+ are investigated. The CaZnOS:Mn2+/epoxy resin composite can simultaneously "feel" (sense) and "see" (image) various types of mechanical stress over a wide energy and frequency range (ultrasonic vibration, impact, friction and compression) as an intense red emission (610 nm) from Mn2+ ions. Further, the accurate linear relation between emission intensity and different stress parameters (intensity, energy and deformation rate) are confirmed.

[Effect of melatonin on proliferation and apoptosis of fibroblasts in human hypertrophic scar].

Objective: To study the effect of melatonin on proliferation and apoptosis of fibroblasts in human hypertrophic scar and its mechanism.

Methods: Fibroblasts from human hypertrophic scar were isolated and cultured with DMEM medium containing 10% FBS, and then they were divided into control (C, added with ethanol), low concentration (LC, added with 1 × 10(-5) mmol/L melatonin), middle concentration (MC, added with 1 × 10(-3) mmol/L melatonin), and high concentration (HC, added with 1 mmol/L melatonin) groups according to the random number table. After being cultured for 24 hours, cell morphologic change was observed under microscope; XTT-PMS assay was used to examine cell proliferative activity; cell cycle and apoptosis were assessed with flow cytometry after double staining of FITC and PI, and the levels of cyclin E, p53, and Fas mRNA were determined with fluorescence quantitative RT-PCR.

[The expression of melatonin receptor in human hypertrophic scar].

Objective: To investigate the expression and its significance of melatonin receptor in human hypertrophic scarring.

Methods: The expression of melatonin receptor GPR50 was detected with immunohistochemistry and the melatonin receptors (MT1, MT2) mRNA were assessed with RT-PCR method in 10 cases of human hypertrophic scar and normal skin. The positive production was sequenced with auto sequencing instrument.

[Effects of Sb3+ on the luminescent properties of Tb3+ doped silicate glass].

The Sb(3+)-doped silicate glasses, Tb(3+)-doped silicate glasses, and Sb3+ and Tb3+ co-doped silicate glasses were synthesized by high-temperature melting method, and their spectral properties were analyzed. The effects of Sb2O3 added as a fining agent on the luminescent properties of Tb(3+)-doped silicate glasses were studied with excitation spectra, emission spectra and decay time. The results show that there is energy transfer from Sb3+ ions to Tb3+ ions in the Sb3+ and Tb3+ co-doped silicate glasses under UV excitation, but the energy transfer efficiency between them is quite low.