Publications by authors named "Juliette Billaud"

Designing electrodes with tailored architecture is an efficient mean to enhance the performance of metal-ion batteries by minimizing electronic and ionic transport limitations and increasing the fraction of active material in the electrode. However, the fabrication of architectured electrodes often involves multiple laborious steps that are not directly scalable to current manufacturing platforms. Here, we propose a processing route in which Cu-coated ZnO powders are directly shaped into architectured electrodes using a simple uniaxial pressing step.

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The search for higher performance, improved safety, and lifetime of lithium-ion batteries relies on the understanding of degradation mechanisms. Complementary to methods and studies on primary particles or crystalline structure on bulk materials, here we use spatially correlated ptychographic X-ray computed nanotomography with a 35 nm resolution and scanning X-ray diffraction microscopy with 1 μm resolution to visualize in 3D the hidden morphological and structural degradation processes in individual secondary particles of lithium-rich nickel, cobalt, and manganese oxides. From comparative examination of pristine and cycled particles, we suggest that morphological degradation could have radial dependency and secondary particle size dependency.

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There is much interest in Na-ion batteries for grid storage because of the lower projected cost compared with Li-ion. Identifying Earth-abundant, low-cost, and safe materials that can function as intercalation cathodes in Na-ion batteries is an important challenge facing the field. Here we investigate such a material, β-NaMnO2, with a different structure from that of NaMnO2 polymorphs and other compounds studied extensively in the past.

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