Green Synthesis of MOF-Based Materials for Electrochemical Reduction of Carbon Dioxide.

Porous ZIF-8 and ZIF-67 were synthesized via a green steam-assisted dry-gel technique and investigated as potential catalysts for CO electroreduction. The synthesis conditions are found to significantly influence the growth of these metal-organic frameworks (MOFs). Notably, the water content employed during synthesis plays a crucial role in shaping the morphological properties of ZIF-8.

Nitridation Temperature Effect on Carbon Vanadium Oxynitrides for a Symmetric Supercapacitor.

In this work, porous carbon-vanadium oxynitride (C-VNO) nanostructures were obtained at different nitridation temperature of 700, 800 and 900 °C using a thermal decomposition process. The X-ray diffraction (XRD) pattern of all the nanomaterials showed a C-VNO single-phase cubic structure. The C-VNO obtained at 700 °C had a low surface area (91.

High performance asymmetric supercapacitor based on molybdenum disulphide/graphene foam and activated carbon from expanded graphite.

Molybdenum disulphide which has a graphene-like single layer structure has excellent mechanical and electrical properties and unique morphology, which might be used with graphene foam as composite in supercapacitor applications. In this work, Molybdenum disulphide (MoS)/graphene foam (GF) composites with different graphene foam loading were synthesized by the hydrothermal process to improve on specific capacitance of the composites. Asymmetric supercapacitor device was fabricated using the best performing MoS/GF composite and activated carbon derived from expanded graphite (AEG) as positive and negative electrodes, respectively, in 6M KOH electrolyte.

High electrochemical performance of hybrid cobalt oxyhydroxide/nickel foam graphene.

In this study, we report the in-situ hydrothermal synthesis of mesoporous nanosheets of cobalt oxyhydroxide (CoOOH) on nickel foam graphene (Ni-FG) substrate, obtained via atmospheric pressure chemical vapour deposition (AP-CVD). The produced composite were closely interlinked with Ni-FG, which enhances the synergistic effect between graphene and the metal hydroxide, CoOOH. It is motivating that the synthesized CoOOH on the Ni-FG substrate showed a homogenous coating of well-ordered intersected nanosheets with porous structure.