Removal efficiencies for 52 pesticides and pharmaceuticals from wastewater effluent by coupling solar heterogeneous photo-oxidation with TiO and infiltration in saturated soil column.

Water resource management has become a hot button issue in recent decades. Countries facing water shortages as a result to climate change must adapt their water supply. The reuse of wastewater treatment plant effluents is becoming increasingly common around the world.

Advances in Photocatalytic Membrane Reactor.

Photocatalytic membrane reactors (PMRs) are a promising technology that combines the benefits of photocatalysis and membrane separation [...

Hybrid system coupling ozonation and nanofiltration with functionalized catalytic ceramic membrane for ibuprofen removal.

The investigations on the removal of ibuprofen (IBU) in a hybrid system coupling ozonation and nanofiltration with functionalized catalytic ceramic membrane are presented. The gaseous ozone into feed water in concentration of 11 g Nm was supplied. Positive influence of catalytic ozonation on ibuprofen decomposition was observed.

Ozone Diffusion through a Hollow Fiber Membrane Contactor for Pharmaceuticals Removal and Bromate Minimization.

Recently, ozonation has been advocated as a solution to tackle emerging contaminants. Hollow fiber membrane contactors (HFMC) have a lower residual ozone concentration than bubble reactors that could limit the formation of potential ozonation by-products, especially bromates that are regulated in drinking water. The aim of this study was to evaluate ozonation with HFMC for pharmaceutical abatement and bromate minimization compared to bubble columns in wastewater.

Understanding Aging Mechanisms in the Context of UV Irradiation of a Low Fouling and Self-Cleaning PVDF-PVP-TiO Hollow-Fiber Membrane.

In the context of designing a photocatalytic self-cleaning/low-fouling membrane, the stability of PVDF-PVP-TiO hollow-fiber membranes under UV irradiation has been studied. The effect of irradiation power, aqueous environment composition and fouling state on the properties of the membranes has been investigated. With this aim, SEM observations, chemical analysis and tensile strength measurements have been conducted.

Impact of Pre-Ozonation during Nanofiltration of MBR Effluent.

This study aimed to investigate the impact of real MBR effluent pre-ozonation on nanofiltration performances. Nanofiltration experiments were separately run with non-ozonated real MBR effluent, ozonated real MBR effluent and synthetic ionic solution mimicking the ionic composition of the real MBR effluent. The specific UV absorbance and the chemical oxygen demand were monitored during ozonation of real effluent, and the mineralization rate was calculated through the quantitative analysis of dissolved organic carbon.

Performance of PVDF-TiO Membranes during Photo-Filtration in the Presence of Inorganic and Organic Components.

In this study, the anti-fouling performance of PVDF-TiO composite membranes, indicated by their permeate flux, was studied with different types of synthetic feed solutions. Photo-filtration (filtration under continuous UV irradiation) of solutions containing inorganic and organic components, which are ubiquitous in drinking/natural water, was performed to evaluate their influence on the photo-induced properties and performance of the membranes. The results indicated that inorganic fouling was unlikely to occur on PVDF-TiO membranes, and the presence of common inorganic ions in drinking water did not hinder their performance.

Influence of Preparation Temperature on the Properties and Performance of Composite PVDF-TiO Membranes.

Composite PVDF-TiO membranes are studied extensively in literature as effective anti-fouling membranes with photocatalytic properties. Yet, a full understanding of how preparation parameters affect the final membrane structure, properties and performance has not been realized. In this study, PVDF-TiO membranes (20 wt% TiO/PVDF) were fabricated via the non-solvent-induced phase separation (NIPS) method with an emphasis on the preparation temperature.

Ozonation using hollow fiber contactor technology and its perspectives for micropollutants removal in water: A review.

Membrane contactor is a device generally used for the removal or the absorption of a gas into another fluid. The membrane acts as a barrier between the two phases and mass transfer occurs by diffusion and not by dispersion. This article is a review of the application of membrane contactor technology for ozonation applied to water treatment.

Ozonation as a pretreatment process for nanofiltration brines: Monitoring of transformation products and toxicity evaluation.

Considerable interest has been given to using nanofiltration (NF) in lieu of reverse osmosis for water reclamation schemes due to lower energy consumption, higher flux rates while ensuring good micropollutants rejection. The application NF results in the generation of a large concentrated waste stream. Treatment of the concentrate is a major hurdle for the implementation of membrane technologies since the concentrate is usually unusable due to a large pollutants content.

Correlation between degradation pathway and toxicity of acetaminophen and its by-products by using the electro-Fenton process in aqueous media.

The evolution of the degradation by-products of an acetaminophen (ACE) solution was monitored by HPLC-UV/MS and IC in parallel with its ecotoxicity (Vibrio fischeri 81.9%, Microtox screening tests) during electro-Fenton (EF) oxidation performed on carbon felt. The aromatic compounds 2-hydroxy-4-(N-acetyl) aminophenol, 1,4-benzoquinone, benzaldehyde and benzoic acid were identified as toxic sub-products during the first stage of the electrochemical treatment, whereas aliphatic short-chain carboxylic acids (oxalic, maleic, oxamic, formic, acetic and fumaric acids) and inorganic ions (ammonium and nitrate) were well identified as non-toxic terminal sub-products.

Influence of volumetric reduction factor during ozonation of nanofiltration concentrates for wastewater reuse.

Global population growth induces increased threat on drinking water resources. One way to address this environmental issue is to reuse water from wastewater treatment plant. The presence of pathogenic microorganisms and potentially toxic organic micropollutants does not allow a direct reuse of urban effluents.

Evidence of solute-solute interactions and cake enhanced concentration polarization during removal of pharmaceuticals from urban wastewater by nanofiltration.

The objective of this paper is to help understanding the distinctive influence of the matrix and of the flux decline (e.g. through the cake enhanced concentration polarization (CECP) phenomenon) on the removal mechanisms of four pharmaceutically active compounds (PhACs) from wastewater treatment plant (WWTP) effluent by nanofiltration (NF).

Toxicity removal assessments related to degradation pathways of azo dyes: Toward an optimization of Electro-Fenton treatment.

The degradation pathway of Acid Orange 7 (AO7) by Electro-Fenton process using carbon felt cathode was investigated via HPLC-UV and LC-MS, IC, TOC analysis and bioassays (Vibrio Fischeri 81.9% Microtox(®) screening tests). The TOC removal of AO7 reached 96.

Study of photocatalytic degradation of tributyltin, dibutylin and monobutyltin in water and marine sediments.

This study reports on the first assessment of the treatment of sediments contaminated by organotin compounds using heterogeneous photocatalysis. Photocatalysis of organotins in water was carried out under realistic concentration conditions (μgL(-1)). Degradation compounds were analyzed by GC-ICP-MS; a quasi-complete degradation of tributyltin (TBT) in water (99.