β-Ketoiminato-based copper(ii) complexes as CVD precursors for copper and copper oxide layer formation.

The synthesis of ketoiminato copper(ii) complexes [Cu(OCRCHC(CH3)NCH2CH2X)(μ-OAc)]2 (X = NMe2: 4a, R = Me; 4b, R = Ph. X = OMe: 5, R = Me) and [Cu(OCRCHCMeNCH2CH2NEt2)(OAc)] (6, R = Me) from RC(O)CHC(CH3)N(H)CH2CH2X (X = NMe2: 1a, R = Me; 1b, R = Ph. X = NEt2: 1c, R = Me.

Magnesium β-ketoiminates as CVD precursors for MgO formation.

The synthesis and characterization of bis(ketoiminato)magnesium(ii) complexes of composition [Mg(OCRCHCHRNCHCHX)] (X = NMe: 3a, R = R = Me; 3b, R = Me, R = Ph. X = OMe: 3c, R = R = Me) are reported. Complexes 3a-c are accessible by the reaction of C(O)RCHCHRN(H)CHCHX (X = NMe: 1a, R = R = Me; 1b, R = Me, R = Ph.

Synthesis of [{AgOCCHOMe(PPh)} ] and theoretical study of its use in focused electron beam induced deposition.

The synthesis, chemical and physical properties of [{AgOCCHOMe} ] () and [{AgOCCHOMe(PPh)} ] () are reported. Consecutive reaction of AgNO with HOCCHOMe gave , which upon treatment with PPh produced . Coordination compound forms a 1D coordination polymer in the solid state as evidenced by single crystal X-ray structure analysis.

Crystal structure of bis-[tetra-kis-(tri-phenyl-phosphane-κP)silver(I)] (nitrilo-tri-acetato-κ(4) N,O,O',O'')(tri-phenyl-phosphane-κP)argentate(I) with an unknown amount of methanol as solvate.

The structure of the title compound, [Ag(C18H15P)4]2[Ag(C6H6NO6)(C18H15P)], exhibits trigonal (P-3) symmetry, with a C 3 axis through all three complex ions, resulting in an asymmetric unit that contains one third of the atoms present in the formula unit. The formula unit thus contains two of the cations, one anion and disordered mol-ecules of methanol as the packing solvent. Attempts to refine the solvent model were unsuccessful, indicating uninter-pretable disorder.

Zirconium and Hafnium Twin Monomers for Mixed Oxides.

The synthesis of Zr and Hf twin monomers of type [M(2-OCH C H O) (x HOCH C H O)] (3, M=Zr, x=0; 4, M=Hf, x=1) and M[(2-OCH -C H O) (2-HOCH -C H OH)] (5, M=Zr; 6, M=Hf) by reacting M(OR) (M=Zr, R= C H , 1; M=Hf, R= C H , 2) with 2-furylmethanol or 2-hydroxybenzyl alcohol is discussed. Complexes 3-6 were homopolymerized under acidic conditions. Additionally, 5 and 6 were copolymerized with 2,2'-spirobi[4 H-1,3,2-benzodioxasiline] (SBS).