Classification of produced water samples using class-oriented chemometrics and comprehensive two-dimensional gas chromatography coupled to mass spectrometry.

Produced water (PW) is a type of wastewater that arises during oil and gas production. Due to its potential environmental impact, PW is one of the most closely monitored forms of wastewater in the petroleum industry. The total oil and grease (TOG) content in the water is a crucial parameter for assessing the environmental impact of PW.

Assessment of the effect of short-term weathering on the molecular-level chemical composition of crude oils in contact with aquatic environments.

Multiple studies have focused on the effect of long-term weathering processes on oils after spill events, without considering the chemical compositional changes occurring shortly after the release of oil into the environment. Therefore, the present study provides a broad chemical characterization for understanding of the changes occurring in the chemical compositions of intermediate (°API = 27.0) and heavy (°API = 20.

Improving selective channel occlusion of complex hydrocarbons and fatty acid methyl esters in urea crystals by using an expendable 3D-printed microfluidic device for sample preparation in untargeted petroleomics.

In this study, we describe a proof-of-concept investigation of the potential and limitations of employing channel occlusion for sample preparation in untargeted analysis in petroleomics. A middle petroleum distillate composed of fatty acid methyl esters (FAME) and a complex mixture of linear, branched, and cyclic hydrocarbons were selected as the model samples for this investigation. A microfluidic device was engineered to overcome the limitations of channel occlusion, resulting in a quick and robust method for sample preparation.