TMV Disk Scaffolds for Making sub-30 nm Silver Nanorings.

Nanosized bioscaffolds can be utilized to tackle the challenge of size reduction of metallic rings owing to their miniature features as well as their well-known biomineralization capacity. The tobacco mosaic virus coat protein is used as a command surface to grow and assemble silver nanoparticles into sub-30 nm rings. The versatility of TMV allows the formation of both solid silver rings and rings consisting of discrete silver nanoparticles.

Nanoring formation via in situ photoreduction of silver on a virus scaffold.

The fabrication of plasmonic nanorings remains of substantial interest by virtue of their enhanced electric and magnetic response to light fields which can be subsequently exploited in diverse applications. Scaling down the size of nanorings holds promise in creating artificial magnetism at wavelengths matching the solar spectrum. Nanosized bioscaffolds can be utilized to tackle the challenge of size reduction of metallic rings owing to their miniature features as well as their well-known biomineralization capacity.

Molecular sensing: modulating molecular conduction through intermolecular interactions.

We observe changes in the molecular conductivity of individual oligophenylene-vinylene (OPV) molecules due to interactions with small aromatic molecules. Fluorescence experiments were correlated with scanning tunneling microscopy measurements in order to determine the origin of the observed effect. Both nitrobenzene and 1,4-dinitrobenzene decreased fluorescence intensity and molecular conductivity, while toluene had no effect.