Manipulation of Gaseous Ions with Acoustic Fields at Atmospheric Pressure.

The ability to controllably move gaseous ions is an essential aspect of ion-based spectrometry (, mass spectrometry and ion mobility spectrometry) as well as materials processing. At higher pressures, ion motion is largely governed by diffusion and multiple collisions with neutral gas molecules. Thus, high-pressure ion optics based on electrostatics require large fields, radio frequency drives, complicated geometries, and/or partially transmissive grids that become contaminated.

Color Transferability from Solution to Solid Using Silica Coated Silver Nanoparticles.

The interpretation of color change in sensors and tests can be linked to incorrect conclusions if the intrinsic color changes are not accounted for. In this work, we study the intrinsic color change associated with the process of embedding nanoparticles in a polymer to create nanocomposite films. We present a safer, faster method to coat silver nanoparticles with silica and employ a seven-factor Plackett-Burman design to identify critical factors in the synthesis.

Tuning Net Charge in Aliphatic Polycarbonates Alters Solubility and Protein Complexation Behavior.

A synthetic strategy yielded polyelectrolytes and polyampholytes with tunable net charge for complexation and protein binding. Organocatalytic ring-opening polymerizations yielded aliphatic polycarbonates that were functionalized with both carboxylate and ammonium side chains in a post-polymerization, radical-mediated thiol-ene reaction. Incorporating net charge into the polymer architecture altered the chain dimensions in phosphate buffered solution in a manner consistent with self-complexation and complexation behavior with model proteins.