Projected changes of the emission and transport of organic pollutants and metals from shipping in European seas 2018-2050.

The ChemicalDrift model is applied to predict concentrations of metals and polycyclic aromatic hydrocarbons emitted from shipping in European seas in 2050, compared to 2018. Sources include antifouling paints (AFPs), discharge water from scrubbers and atmospheric deposition. The fate of pollutants in the marine environment is presented, highlighting the effect of degradation and volatilization, with seasonal and regional differences.

Measurement and Modeling of Ship-Related Ultrafine Particles and Secondary Organic Aerosols in a Mediterranean Port City.

Maritime transport emerges as a major source of ultrafine particle (UFP) pollution in coastal regions with consequences for the health of people living in port cities. Inhalation of UFPs can cause inflammation and oxidative stress, which are starting points for further diseases. In addition to primary particles, secondary organic aerosol (SOA) may form through the photo-oxidation of volatile organic compounds emitted in ship exhaust.

Cumulative environmental risk assessment of metals and polycyclic aromatic hydrocarbons from ship activities in ports.

Marine environmental risk assessments rarely consider the cumulative risk from multiple contaminants and sources. Ships give rise to a range of contaminants, originating from different onboard sources, resulting in contaminant loads to the marine environment. Here, the Ship Traffic Emission Assessment Model (STEAM), in combination with the hydrodynamic and chemical fate model MAMPEC, was used to calculate loads and predicted environmental concentrations (PECs) of metals and polycyclic aromatic hydrocarbons, in four ports.

Invisible ship tracks show large cloud sensitivity to aerosol.

Cloud reflectivity is sensitive to atmospheric aerosol concentrations because aerosols provide the condensation nuclei on which water condenses. Increased aerosol concentrations due to human activity affect droplet number concentration, liquid water and cloud fraction, but these changes are subject to large uncertainties. Ship tracks, long lines of polluted clouds that are visible in satellite images, are one of the main tools for quantifying aerosol-cloud interactions.

Underwater noise emissions from ships during 2014-2020.

This paper reports trends in the input of underwater noise source energy emission from global shipping, based on bottom-up modeling of individual ships. In terms of energy, we predict the doubling of global shipping noise emissions every 11.5 years, on average, but there are large regional differences.

Metal and PAH loads from ships and boats, relative other sources, in the Baltic Sea.

The Baltic Sea is a sensitive environment that is affected by chemical pollution derived from multiple natural and anthropogenic sources. The overall aim of this study was to estimate the load of metals and polycyclic aromatic hydrocarbons (PAHs) from shipping and leisure boating, relative other sources, to the Baltic Sea and to identify possible measures that could lead to major reductions in the loads of hazardous substances from maritime shipping and leisure boating. The use of copper-based antifouling paints, and operation of scrubbers in open loop mode, were the two most dominant identified sources of hazardous substances to the Baltic Sea.

Real-world particle emissions and secondary aerosol formation from a diesel oxidation catalyst and scrubber equipped ship operating with two fuels in a SECA area.

SO Emissions Control Areas (SECAs) have been established to reduce harmful effects of atmospheric sulfur. Typical technological changes for ships to conform with these regulations have included the combustion of low-sulfur fuels or installment of SO scrubbers. This paper presents experimental findings from high-end real-time measurements of gaseous and particulate pollutants onboard a Roll-on/Roll-off Passenger ship sailing inside a SECA equipped with a diesel oxidation catalyst (DOC) and a scrubber as the exhaust aftertreatment.

Evaluation of Methane Emissions Originating from LNG Ships Based on the Measurements at a Remote Marine Station.

We analyzed pollution plumes originating from ships using liquefied natural gas (LNG) as a fuel. Measurements were performed at a station located on the Utö island in the Baltic Sea during 2015-2021 when vessels passed the station along an adjacent shipping lane and the wind direction allowed the measurements. The ratio of the measured concentration peaks ΔCH/ΔCO ranged from 1% to 9% and from 0.

Modelling spatial dispersion of contaminants from shipping lanes in the Baltic Sea.

Major sources of pollution from shipping to marine environments are antifouling paint residues and discharges of bilge, black, grey and ballast water and scrubber discharge water. The dispersion of copper, zinc, naphthalene, pyrene, and dibromochloromethane have been studied using the Ship Traffic Emission Assessment Model, the General Estuarine Transport Model, and the Eulerian tracer transport model in the Baltic Sea in 2012. Annual loads of the contaminants ranged from 10 tons for pyrene to 100 s of tons for copper.

Framework for the environmental impact assessment of operational shipping.

Shipping is an important source of pollution affecting both atmospheric and aquatic environments. To allow for efficient mitigation of environmental degradation, it is essential to know the extent of the impacts of shipping in relation to other sources of pollution. Here, we give a perspective on a holistic approach to studies of the environmental impacts of operational shipping through presentation of an assessment framework developed and applied on a case of shipping in the Baltic Sea.

Estimating the health and economic burden of shipping related air pollution in the Iberian Peninsula.

Air pollution is the leading cause of the global burden of disease from the environment, entailing substantial economic consequences. International shipping is a significant source of NO, SO, CO and PM, which can cause known negative health impacts. Thus, this study aimed to estimate the health impacts and the associated external costs of ship-related air pollution in the Iberian Peninsula for 2015.

Assessing the costs and environmental benefits of IMO regulations of ship-originated SOx and NOx emissions in the Baltic Sea.

To assess the value of the environmental benefits of the Sulphur Emission regulation (SECA) that came into force in 2015, changes in depositions of SOx and NOx from ship exhaust gas emissions were modelled and monetized for the Baltic Sea region for the years 2014 and 2016. During this period, the total deposition of SOx in the study area decreased by 7.3%.

Shipping Remains a Globally Significant Source of Anthropogenic PN Emissions Even after 2020 Sulfur Regulation.

Shipping is the main source of anthropogenic particle emissions in large areas of the globe, influencing climate, air quality, and human health in open seas and coast lines. Here, we determined, by laboratory and on-board measurements of ship engine exhaust, fuel-specific particle number (PN) emissions for different fuels and desulfurization applied in shipping. The emission factors were compared to ship exhaust plume observations and, furthermore, exploited in the assessment of global PN emissions from shipping, utilizing the STEAM ship emission model.

Health Impact of Air Pollution from Shipping in the Baltic Sea: Effects of Different Spatial Resolutions in Sweden.

In 2015, stricter regulations to reduce sulfur dioxide emissions and particulate air pollution from shipping were implemented in the Baltic Sea. We investigated the effects on population exposure to particles <2.5 µm (PM) from shipping and estimated related morbidity and mortality in Sweden's 21 counties at different spatial resolutions.

Modeling of the Concentrations of Ultrafine Particles in the Plumes of Ships in the Vicinity of Major Harbors.

Marine traffic in harbors can be responsible for significant atmospheric concentrations of ultrafine particles (UFPs), which have widely recognized negative effects on human health. It is therefore essential to model and measure the time evolution of the number size distributions and chemical composition of UFPs in ship exhaust to assess the resulting exposure in the vicinity of shipping routes. In this study, a sequential modelling chain was developed and applied, in combination with the data measured and collected in major harbor areas in the cities of Helsinki and Turku in Finland, during winter and summer in 2010-2011.

Shipborne nutrient dynamics and impact on the eutrophication in the Baltic Sea.

The Baltic Sea is a severely eutrophicated sea-area where intense shipping as an additional nutrient source is a potential contributor to changes in the ecosystem. The impact of the two most important shipborne nutrients, nitrogen and phosphorus, on the overall nutrient-phytoplankton-oxygen dynamics in the Baltic Sea was determined by using the coupled physical and biogeochemical model system General Estuarine Transport Model-Ecological Regional Ocean Model (GETM-ERGOM) in a cascade with the Ship Traffic Emission Assessment Model (STEAM) and the Community Multiscale Air Quality (CMAQ) model. We compared two nutrient scenarios in the Baltic Sea: with (SHIP) and without nutrient input from ships (NOSHIP).

Cleaner fuels for ships provide public health benefits with climate tradeoffs.

We evaluate public health and climate impacts of low-sulphur fuels in global shipping. Using high-resolution emissions inventories, integrated atmospheric models, and health risk functions, we assess ship-related PM pollution impacts in 2020 with and without the use of low-sulphur fuels. Cleaner marine fuels will reduce ship-related premature mortality and morbidity by 34 and 54%, respectively, representing a ~ 2.

Risk assessment of bilge water discharges in two Baltic shipping lanes.

Environmental concentrations and effects of bilge water contaminants in two Baltic Sea areas were estimated from modelling of discharge rates and analytical data on bilge water from seven ships. Biodegradation of bilge water oil was accounted for and annual water concentrations were estimated to peak in late spring, which coincides with the beginning of a period with extensive biological activities in the sea. Concentrations on bilge water metals were calculated both as water concentrations and as the annual contribution of metals to sediments.

Costs and benefits of low-sulphur fuel standard for Baltic Sea shipping.

The maximum allowable fuel sulphur content for shipping in the Baltic Sea dropped from 1%S to 0.1%S in 1 January 2015. We provide a cost-benefit analysis of the sulphur reduction policy in the Baltic Sea Sulphur Emission Control Area (SECA).

A comprehensive inventory of the ship traffic exhaust emissions in the Baltic Sea from 2006 to 2009.

This study addresses the exhaust emissions of CO₂, NO(x), SO(x), CO, and PM(2.5) originated from Baltic Sea shipping in 2006-2009. Numerical results have been computed using the Ship Traffic Emissions Assessment Model.

The erratic emission of pyrene on gold nanoparticles.

Gold nanoparticles functionalized with chromophores are known to present unpredictable fluorescence as a function of their structure. Odd-even effects, based on the number of methylene units of the chain to which the fluorophore is attached, and the nature of the anchoring group on the gold surface have, in the past, been suggested to be responsible for the behavior. Here we investigate the fluorescence processes of two newly synthesized pyrene derivatives bound to gold nanoparticles.

A computational study of the adsorption of small Ag and Au nanoclusters on graphite.

The adsorption of silver and gold atoms, and M2, M6, and M13 (M=Ag or Au) clusters on the (0001) graphite surface has been investigated computationally using the density functional theory (DFT) with periodic boundary conditions and plane wave basis functions. The surface has been modeled as a single carbon sheet. The role of dispersion forces has been studied with an empirical classical model.

Quantum chemical interaction energy surfaces of ethylene and propene dimers.

Ab initio studies of nonbonding interactions for ethylene and propene dimers were conducted at the MP2/6-311+G(2df,2pd) level. The dimers were attractive in all of the orientations studied; however, the attraction was <0.1 kcal/mol for ethylene D2h and C2h dimers, for which the pi-electron clouds or H atoms interact closely.

Surface enhanced second harmonic generation from macrocycle, catenane, and rotaxane thin films: experiments and theory.

Surface enhanced second harmonic generation (SE SHG) experiments on molecular structures, macrocycles, catenanes, and rotaxanes, deposited as monolayers and multilayers by vacuum sublimation on silver, are reported. The measurements show that the molecules form ordered thin films, where the highest degree of order is observed in the case of macrocycle monolayers and the lowest in the case of rotaxane multilayers. The second harmonic generation activity is interpreted in terms of electric field induced second harmonic (EFISH) generation where the electric field is created by the substrate silver atoms.