The modification of protein-stabilized gold nanoclusters with fluorophores has been intensively applied for the ratiometric detection of biomolecules, metal ions, and anions. This study developed a straightforward strategy to prepare lysozyme nanoparticle-encapsulated gold nanoclusters (LysNP-AuNCs) as a dual-emission probe for the ratiometric sensing of cyanide through fluorescence resonance energy transfer (FRET) without the conjugation of additional fluorophores. The reduction of gold ion precursors with lysozyme generated lysozyme-stabilized AuNCs under an alkaline pH, which were demonstrated to self-assemble into nanoaggregates during the formation of AuNCs.
View Article and Find Full Text PDFIn order to determine the stand age in the uneven-aged natural forest, a dynamic prediction model of stand volume and biomass was established in this study. In the model, the site quality grade was used as the dumb variable and the interval was used as the independent variable. In addition, the parameters of the model were estimated using immune evolutionary algorithm.
View Article and Find Full Text PDFThree diesel-dominated routes (DDRs) and three gasoline-dominated routes (GDRs) were chosen as the study sites. The total number of vehicles on GDRs (47,200) was much higher than that on DDRs (14,500). The concentration of polycyclic aromatic hydrocarbons (PAHs), elemental carbon, organic carbon, and metals from GDR roadsides was higher than that for DDRs.
View Article and Find Full Text PDFThis study investigates the effects of fly ash compositions (SiO(2) and Al(2)O(3)), particle sizes (4-10 μm and 40 μm), and concentrations on the simultaneous removals of fly ash and NO using a fluidized-bed catalyst reactor. Experimental results show that the removal efficiencies of fly ash and NO at particle concentrations of 968-11,181 mg m(-3) are 71-97% and 42-57%, respectively. SiO(2) particles have more influences than Al(2)O(3) particles on the performances of fluidized-bed CuO/AC catalyst.
View Article and Find Full Text PDFJ Hazard Mater
November 2009
The filtration of SiO(2), Al(2)O(3) and Fe(2)O(3) particles with average sizes of 4 and 40 microm using a fluidized bed filter at 40 and 300 degrees C was studied. The collection mechanisms, interparticle forces and bounce-off effect between filtered particles and collectors were analyzed to determine their effect on particle filtration. Experimental results showed that the collection efficiency of 4 microm SiO(2) and Al(2)O(3) particles exceeded that of 40 microm particles.
View Article and Find Full Text PDFLarge-scale open burning of joss paper is an important ritual practice for deity worshipping during Buddhist and Taoist festivals. Since Buddhism and Taoism are two of the most popular religions in Chinese societies and some Asian countries, the impact of joss paper burning on the air quality needs further investigation. This study explores the concentrations of polycyclic aromatic hydrocarbons (PAHs) in ambient air during one of the most important festivals, in which large-scale burning of joss paper occurs in temples and in people's houses.
View Article and Find Full Text PDFAerosol samples for dry deposition and total suspend particulates (TSP) were collected from August to November of 2003 in central Taiwan. Ion chromatography was used to analyze the related water-soluble ionic species (Cl(-), NO(3)(-), SO(4)(2-), Na(+), NH(4)(+), K(+), Mg(2+) and Ca(2+)). The results obtained in this study indicated that the ambient air particulate mass concentrations in the daytime period (averaged 975.
View Article and Find Full Text PDFThe purpose of this study is to characterize metallic elements associated with atmospheric particulate matter of total suspended particulate (TSP), fine particle (particle matter with aerodynamical diameter <2.5 microm, PM(2.5)), coarse particle (particle matter with aerodynamical diameter 2.
View Article and Find Full Text PDFA micro-orifice uniform deposit impactor (MOUDI) and a nano-MOUDI were used to measure the atmospheric coarse (PM2.5-10), fine (PM2.5), ultrafine (PM0.
View Article and Find Full Text PDFThe purpose of this study was to characterize metallic elements associated with atmospheric particulate matter in total suspended particulate (TSP), fine particles (particle matter with an aerodynamic diameter of <2.5 microm, PM2.5) and coarse particles (particle matter with an aerodynamic diameter of 2.
View Article and Find Full Text PDFThe characterization for water-soluble species of total suspended particulate (TSP), dry deposition flux, and dry deposition velocity (V(d)) were studied at Taichung Harbor (TH) and Wuchi traffic sampling sites at offshore sampling site near Taiwan Strait of central Taiwan during March 2004-January 2005. The average concentrations of TSP and dry deposition flux at the TH sampling site were higher than at the WT sampling site during the sampling period. The samples collected were analyzed by a ion chromatography (DIONEX-100) for the ionic species (Cl(-), SO(4)(2-), NO(3)(-), NH(4)(+), Na(+), Ca(2+), and Mg(2+)) analysis.
View Article and Find Full Text PDFA micro-orifice uniform deposit impactor (MOUDI) and a nano-MOUDI were used to measure the atmospheric coarse (PM2.5 -10), fine (PM2.5), ultrafine (PM0.
View Article and Find Full Text PDFToxicol Ind Health
October 2005
Anthropogenic acid precursor emissions in Asia are increasing at a significant rate and this is expected to continue for the next several years. This paper comprises of studies that included sulfate, nitrate and ammonium around Asian countries (China, Korea, Japan and Taiwan) in recent years. The paper also provides the water-soluble ionic fine and coarse particulate concentrations in these Asian countries in recent years.
View Article and Find Full Text PDFAir aerosol samples for TSP (total suspended particulate), coarse particulate (particle matter with aerodynamical diameter 2.5-10 microm, PM(2.5-10)), fine particulate (particle matter with aerodynamical diameter <2.
View Article and Find Full Text PDFThe concentrations of total suspended particulate (TSP), fine particles PM(2.5) (with aerodynamic diameter <2.5 microm), coarse particles PM(2.
View Article and Find Full Text PDFThe characterization for watersoluble species of dry deposition flux, total suspended particulate (TSP), fine particle (particle matter with aerodynamical diameter 2.5 microm, PM2.5), coarse particle (particle matter with aerodynamical diameter 2.
View Article and Find Full Text PDFAerosol samples were collected by total suspended particulate (TSP) and dry deposition plate (downward, upward) from August to November in 2003 in central Taiwan. The particulate metallic elements (Fe, Pb, Zn, Cu, Mg and Mn) were also measured in this study during the summer and autumn periods of 2003. The results obtained in this study indicated that the ambient air particulate mass concentrations in the daytime period (averaged 975.
View Article and Find Full Text PDFDownward, upward dry deposition fluxes and total suspended particulate of particulate heavy metals (Fe, Pb, Zn, Cu, Mg and Mn) were measured in daytime and nighttime period in Sha-Lu, a small city in the central Taiwan during summer period of 2003. The results showed that the total suspended particulate concentrations of particulate mass in the daytime period (averaged 996.2 g/m3) were higher than in nighttime period (averaged 560.
View Article and Find Full Text PDFAmbient suspended particulate (dry deposition, TSP) was collected in the traffic sites Sha-Lu, central Taiwan. In addition, the related water-soluble ionic species (Cl-, NO3(-), SO4(2-), Na+, NH4(+), K+, Mg2+ and Ca2+) were analysed and wind speed, wind direction and temperature were also measured in this study. The downward dry deposition fluxes (averaged 54.
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