Structural relaxation in layered, non-stoichiometric FeS.

In this study, we investigate the kinetics of the enantiotropic solid-solid β-transition in Fe7S8 pyrrhotite, which presents a prominent example of a metal-nonmetal compound with layered crystal structure. The low-temperature (4C) and high-temperature (1C) modifications differ in their crystallographic unit-cell dimension, vacancy distribution, and magnetic ordering in the crystal lattice. Fast differential scanning calorimetry (FDSC) reveals that cooling of the paramagnetic 1C phase below the transformation temperature Tβ = 597 K, which is also the Curie temperature, generates a metastable phase that transforms into the ferrimagnetic 4C phase with high vacancy order upon further annealing below Tβ.