Publications by authors named "Judith Jeevarajan"

This work delineates the thermal safety of full-scale sodium-ion batteries (SIBs) by interrogating the material-level electrochemical and thermal responses of micro and nano-structured tin (Sn) based anodes and sodium vanadium phosphate (NVP) cathodes in suitable electrolyte systems. Informed by these material-level signatures, we delineate cell-level thermal safety maps cognizant of underlying electrode-electrolyte interactions in SIBs.

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Lithium-ion batteries continue to transform consumer electronics, mobility, and energy storage sectors, and the applications and demands for batteries keep growing. Supply limitations and costs may lead to counterfeit cells in the supply chain that could affect quality, safety, and reliability of batteries. Our research included studies of counterfeit and low-quality lithium-ion cells, and our observations on the differences between these and original ones, as well as the significant safety implications, are discussed.

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Article Synopsis
  • An experimental setup and standard operating procedure (SOP) are created to gather detailed data on gas emissions and fire behavior during the thermal runaway of lithium-ion battery cells.
  • The experiments involve conditioning a 18650 cylindrical cell to various states-of-charge, then inducing thermal runaway with a controlled heating method while measuring gas concentrations and observing key events using camcorders.
  • The collected data helps analyze the cell's characteristics, such as gas compositions and mass loss, which can aid in developing models for understanding lithium-ion battery fires and could be adapted for different cell types.
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This report is the first effort to use atomic layer deposition method for deposition of nanosized-thin and highly conformal Al(2)O(3) coatings onto LiMn(2)O(4) cathodes with precise thickness-control at atomic scale. The coated cathodes exhibit significantly enhanced cycleability than bare cathodes, as the dense ALD coating protects the cathode material from severe dissolution.

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