Electro-optic crosslinkable chromophores with ultrahigh electro-optic coefficients and long-term stability.

The development of organic electro-optic materials with ultrahigh electro-optic coefficients and high long-term alignment stability is the most challenging topic in this field. Next-generation crosslinkable nonlinear optical chromophore molecular glasses were developed to address this problem. A highly stable EO system including crosslinkable binary chromophores QLD1 and QLD2 or crosslinkable single chromophore QLD3 and multichromophore QLD4 with large hyperpolarizability was synthesized using tetrahydroquinoline as the donor.