Pt-TiO systems are the most widely used photocatalysts in the production of green hydrogen from glycerol photoreforming. To incorporate metals on the surface of materials, photodeposition is the most used method because it employs mild conditions. However, despite its use, there are some parameters that have not been deeply studied, such as the appropriate metal loading and the method itself, to obtain a better dispersion of Pt.
View Article and Find Full Text PDFRed grapes and blueberries are known for their high content of bioactive compounds and antioxidant properties. In Mediterranean winemaking, traditional sun-drying can be replaced by controlled-airflow-chamber-drying, which provides better quality, higher phenolic content, and increased antioxidants. This study aimed to increase the sugar content and phenolic compounds of the must by drying the fruits to fifty per cent of their original moisture content.
View Article and Find Full Text PDFNanomaterials (Basel)
April 2023
Several biochars were synthesized from olive stones and used as supports for TiO, as an active semiconductor, and Pt as a co-catalyst (Pt/TiO-PyCF and Pt/TiO-AC). A third carbon-supported photocatalyst was prepared from commercial mesoporous carbon (Pt/TiO-MCF). Moreover, a Pt/TiO solid based on Evonik P25 was used as a reference.
View Article and Find Full Text PDFHydrogen production is mainly based on the use of fossil fuels, but currently, many alternative routes are being developed, among which the photo-reforming of oxygenated organic compounds stands out. Recently, several studies have been carried out in order to develop new techniques to create bio-inspired TiO structures. One of these is 'biotemplating', a process that replicates a biological system in an inorganic TiO-based structure.
View Article and Find Full Text PDFFlavonoid compounds, including anthocyanins and flavan-3-ol derivatives, total tannins, total vitamin C and resveratrol were analyzed by HPLC in blueberry fruits, their skin and pulp, as well as in wines produced from them. Two wines were elaborated, with different times of fermentation. The fruit analysis provided information on the distribution of bioactive compounds in the berries, showing that the skin had the highest concentrations of all compounds.
View Article and Find Full Text PDFThis article explores the effect of the synthetic method of titanium dioxide (TiO)/C composites (physical mixture and the water-assisted/unassisted sol-gel method) on their photocatalytic activity for hydrogen production through glycerol photoreforming. The article demonstrates that, apart from a high surface area of carbon and the previous activation of its surface to favor titania incorporation, the appropriate control of titania formation is crucial. In this sense, even though the amount of incorporated titania was limited by the saturation of carbon surface groups (in our case, ca.
View Article and Find Full Text PDFOlive leaves (by-product from olive oil production in olive mills) were used as biotemplates to synthesize a titania-based artificial olive leaf (AOL). Scanning electron microscopy (SEM) images of AOL showed the successful replication of trichomes and internal structure channels present in olive leaves. The BET surface area of AOL was 52 m·g.
View Article and Find Full Text PDFBackground: Drying is one of the traditional methods used for the conservation of fruits. In recent years, different methods have been developed to obtain higher quality products. Chamber-drying methods with hot air at controlled temperature are reliable and easy to use.
View Article and Find Full Text PDF