Publications by authors named "Juan Ignacio Gonzalez-Perez"
Article Synopsis
- Researchers synthesized a trimetallic sulfide cluster [Ta(η-CMe)Cl(μ-Cl)(μ-S)(μ-S)] (2) by reacting (MeSi)S and [Ta(η-CMe)Cl] in a 4:3 ratio, resulting in the loss of SiClMe.
- A similar reaction with a different ratio produced another identical complex (3), and X-ray diffraction confirmed the trinuclear structure of both clusters.
- Further thermal treatment of cluster 2 yielded a dinuclear tantalum(IV) sulfide complex (4), which could also be synthesized directly using a one-pot method; derivatives of 4 were created through reactions with alkylating agents, showcasing interesting trans-cis
