Thermal coating paints offer a passive strategy to reduce heat gain in buildings, improve ventilation, and lower energy consumption. This study investigates the effectiveness of these technologies by comparing different housing structures and environmental conditions. Specifically, it examines thermal envelope solutions for cool roofs in homes along the Colombian Caribbean Coast.
View Article and Find Full Text PDFIn this work, we design and implement a new bifocal diffractive spiral lens within an optical tweezers system. The proposed diffractive optical element coined Kolokaski Kinoform Spiral Lens (KKSL), generates twin optical vortices along the propagation direction. The axial positions, as well as the diameters of the generated vortex beams, are correlated with the Kolakoski aperiodic sequence introduced in the design of the diffractive lens.
View Article and Find Full Text PDFThe design and implementation of a multiplexed spiral phase mask in an experimental optical tweezers setup are presented. This diffractive optical element allows the generation of multiple concentric vortex beams with independent topological charges and without amplitude modulation. The generalization of the phase mask for multiple concentric vortices is also shown.
View Article and Find Full Text PDFThe present article is a continuation of our previous works on the anomalies in the decay rates and the capacitance measurements inside a modified Faraday cage. Here we present the anomalous variations in the measurements of inductance when a coil is placed inside an interleaving structure of metal and organic material. The fluctuation in the inductance values was found to be in the range - 0.
View Article and Find Full Text PDFThe irradiation of spherical gold nanoparticles (AuNPs) with nanosecond laser pulses induces shape transformations yielding nanocrystals with an inner cavity. The concentration of the stabilizing surfactant, the use of moderate pulse fluences, and the size of the irradiated AuNPs determine the efficiency of the process and the nature of the void. Hollow nanocrystals are obtained when molecules from the surrounding medium (e.
View Article and Find Full Text PDFA four-dimensional potential energy surface (PES) for the interaction between a rigid carbon dioxide molecule and a rigid nitrogen molecule was constructed based on quantum-chemical ab initio calculations up to the coupled-cluster level with single, double, and perturbative triple excitations. Interaction energies for a total of 1893 points on the PES were calculated using the counterpoise-corrected supermolecular approach and basis sets of up to quintuple-zeta quality with bond functions. The interaction energies were extrapolated to the complete basis set limit, and an analytical site-site potential function with seven sites for carbon dioxide and five sites for nitrogen was fitted to the interaction energies.
View Article and Find Full Text PDFThe collisional dynamics of N2 (+)((2)Σg (+)) cations with Ar atoms is studied using quasi-classical simulations. N2 (+)-Ar is a proxy to study cooling of molecular ions and interesting in its own right for molecule-to-atom charge transfer reactions. An accurate potential energy surface (PES) is constructed from a reproducing kernel Hilbert space (RKHS) interpolation based on high-level ab initio data.
View Article and Find Full Text PDFThe O((3)P) + NO((2)Π) → O2(X(3)Σg(-)) + N((4)S) reaction is among the N- and O- involving reactions that dominate the energetics of the reactive air flow around spacecraft during hypersonic atmospheric re-entry. In this regime, the temperature in the bow shock typically ranges from 1000 to 20,000 K. The forward and reverse rate coefficients for this reaction derived directly from trajectory calculations over this range of temperature are reported in this letter.
View Article and Find Full Text PDFReactions involving N and O atoms dominate the energetics of the reactive air flow around spacecraft when reentering the atmosphere in the hypersonic flight regime. For this reason, the thermal rate coefficients for reactive processes involving O((3)P) and NO((2)Π) are relevant over a wide range of temperatures. For this purpose, a potential energy surface (PES) for the ground state of the NO2 molecule is constructed based on high-level ab initio calculations.
View Article and Find Full Text PDFMolecular dynamics simulations of NO-doped Ar solid upon Rydberg photoexcitation of the impurity have been carried out taking into account angular dependent potential energy surfaces (PESs) in the ground and excited states. To go beyond isotropic potentials simulations, the effects of anisotropy of potentials on the structure, dynamics, and energetics are investigated by taking into account two cases, namely, the whole PESs and the isotropic parts. Results have been compared to those obtained in previous works for similar NO-doped rare gas systems.
View Article and Find Full Text PDFMore complete molecular dynamics simulations of NO doped Ar solid upon photoexcitation of the impurity should include effects of angular variations of Ar-NO intermolecular potential. This is the main reason for presenting in this work an ab initio study of the Ar-NO(A (2)Sigma(+)) intermolecular potential. Ab initio calculations were carried out at the level of CASSCF-MRCI, with the aug-cc-pVTZ basis sets.
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