Rational Fabrication of a Robust, Exfoliatable Catechol-Porphyrin Covalent Network for Enhanced HO Photosynthesis.

Covalent organic frameworks (COFs) containing dioxin-linkages are highly valued for their exceptional chemical stability, which is essential for practical use. However, research on dioxin-based COFs remains limited. Herein, a unique nonplanar 2D COF, designated as TCP-COF, constructed from catechol-porphyrin units interconnected by 1,4-dioxin bonds, exhibiting a staggered AAA stacking pattern, is presented.