Publications by authors named "Joseph Prestigiacomo"

Polycrystalline LiMoO was prepared in a sealed Mo crucible at 1380 °C for 48 h using the conventional high-temperature solid-state method. The polar tetragonal crystal structure (space group 4) is confirmed based on the Rietveld refinement of powder neutron diffraction and Li/Li solid-state NMR. The crystal structure features infinite chains of MoO (i.

View Article and Find Full Text PDF

We have directly written nanoscale patterns of magnetic ordering in FeRh films using focused helium-ion beam irradiation. By varying the dose, we pattern arrays with metamagnetic transition temperatures that range from the as-grown film temperature to below room temperature. We employ transmission electron microscopy, X-ray diffraction, and temperature-dependent transport measurements to characterize the as-grown film, and magneto-optic Kerr effect imaging to quantify the He irradiation-induced changes to the magnetic order.

View Article and Find Full Text PDF

A metamaterial approach is capable of drastically increasing the critical temperature, , of composite metal-dielectric superconductors as demonstrated by the tripling of that was observed in bulk Al-AlO coreshell metamaterials. A theoretical model based on the Maxwell-Garnett approximation provides a microscopic explanation of this effect in terms of electron-electron pairing mediated by a hybrid plasmon-phonon excitation. We report an observation of this excitation in Al-AlO core-shell metamaterials using inelastic neutron scattering.

View Article and Find Full Text PDF

One of the most important goals of condensed matter physics is materials by design, i.e. the ability to reliably predict and design materials with a set of desired properties.

View Article and Find Full Text PDF

Recent experiments have shown the viability of the metamaterial approach to dielectric response engineering for enhancing the transition temperature, Tc, of a superconductor. In this report, we demonstrate the use of Al2O3-coated aluminium nanoparticles to form the recently proposed epsilon near zero (ENZ) core-shell metamaterial superconductor with a Tc that is three times that of pure aluminium. IR reflectivity measurements confirm the predicted metamaterial modification of the dielectric function thus demonstrating the efficacy of the ENZ metamaterial approach to Tc engineering.

View Article and Find Full Text PDF

We present the structure of Ln(30)Ru(4+x)Sn(31-y) (Ln = Gd, Dy) and the anisotropic resistivity, magnetization, thermopower, and thermal conductivity of single crystal Ln(30)Ru(4+x)Sn(31-y) (Ln = Gd, Tb). Gd(30)Ru(4.92)Sn(30.

View Article and Find Full Text PDF

New distorted variants of the cubic BaHg11 structure type have been synthesized in Ga flux. Multiple phases of CePd3+xGa8-x, which include an orthorhombic Pmmn structure (x = 3.21(2)), a rhombohedral R3m structure (x = 3.

View Article and Find Full Text PDF